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Thiols, disulfides, and sulfonamides form a group of S(II)\u2010containing precursors, which are used in oxidative amination reactions. An important and versatile group for oxidative amination is represented with S(IV)\u2010containing compounds, i.\u2009e., sufinates, sulfinamides, DMSO, <jats:italic>N<\/jats:italic>\u2010sulfinyl\u2010<jats:italic>O<\/jats:italic>\u2010(<jats:italic>tert<\/jats:italic>\u2010butyl)hydroxylamine, etc. A series of S(VI)\u2010containing precursors for amination reactions (except sulfonyl halides) include sulfonic acids, sulfonyl azides, thiosulfonates, and sulfones. All approaches are represented with the most prominent examples of the resulting sulfonamides, which could be obtained in high yields mostly via short reaction sequences. 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