{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,23]],"date-time":"2026-06-23T04:21:03Z","timestamp":1782188463298,"version":"3.54.5"},"reference-count":58,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2024,8,2]],"date-time":"2024-08-02T00:00:00Z","timestamp":1722556800000},"content-version":"vor","delay-in-days":1,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["The Chemical Record"],"published-print":{"date-parts":[[2024,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Nitrogen oxides (NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>) should be purified according to environmental regulations, being restricted increasingly year by year. A wide variety of denitration technologies, such as selective catalytic reduction (SCR) of NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> to nitrogen (N<jats:sub>2<\/jats:sub>) and NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> storage reduction (NSR) to N<jats:sub>2<\/jats:sub> by injecting reducing agents like ammonia (NH<jats:sub>3<\/jats:sub>), has so far been developed practically. Sophisticated catalytic approaches are perhaps mandatory for the sustainability in energy including complete purification of NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>. As one of the solutions to overcome problems for environment and resource simultaneously, this concept article focuses on the utilization of reactive nitrogen (N<jats:sub><jats:italic>r<\/jats:italic><\/jats:sub>) compounds, mainly NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>, for encouraging an opening to consider nitrogen circular economy. For the recycling of NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> via NH<jats:sub>3<\/jats:sub>, a challenging but rational catalytic technology can be proposed by an alternate switching the inlet gas between NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> containing oxidative gas and H<jats:sub>2<\/jats:sub> containing reductive one without an operation to change the reaction temperature. Considering the reactivity of NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> higher than that of N<jats:sub>2<\/jats:sub>, this kind of NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> to NH<jats:sub>3<\/jats:sub> (NTA) process is promising for synthesizing NH<jats:sub>3<\/jats:sub>, being valuable not only as fertilizer but also as fuel in near future.<\/jats:p>","DOI":"10.1002\/tcr.202400094","type":"journal-article","created":{"date-parts":[[2024,8,2]],"date-time":"2024-08-02T11:01:15Z","timestamp":1722596475000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Utilization of Reactive Nitrogen Compounds for Nitrogen Circular Economy"],"prefix":"10.1002","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5184-046X","authenticated-orcid":false,"given":"Tatsuo","family":"Kimura","sequence":"first","affiliation":[{"name":"National Institute of Advanced Industrial Science and Technology (AIST) Sakurazaka, Moriyama-ku  Nagoya 463-8560 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,2]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100168g"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr800496f"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00202"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202001024"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201800392"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8RE00284C"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.0c03685"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SE00979F"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfueco.2022.100064"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2009.11.036"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2016.09.044"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms7731"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1134-2"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-023-00292-9"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2595"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.2c02926"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306726"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311752"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00714F"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NR06151E"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14687"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400033"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011676"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202102526"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC04432G"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2018.10.036"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.10.069"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY01084K"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.2c06207"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2011.02.052"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2023.128867"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-018-0104-7"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-019-0356-0"},{"key":"e_1_2_7_34_1","unstructured":"UNEP Frontiers 2018\/2019: Emerging Issues of Environmental Concerns UN Environment Programme Nairobi 2019."},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY00061E"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CY01793H"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c01249"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp8060812"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CY01166G"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2014.12.033"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03396"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.2c05705"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CP04761F"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CY00169E"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.8b02880"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ01319A"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC04703D"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20190222"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT00719J"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.122791"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202005473"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature20782"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.7b03733"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA07052B"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP02909C"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar6611"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA02644E"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00857A"}],"container-title":["The Chemical Record"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/tcr.202400094","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,8,30]],"date-time":"2024-08-30T15:09:40Z","timestamp":1725030580000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/tcr.202400094"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,8]]},"references-count":58,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2024,8]]}},"alternative-id":["10.1002\/tcr.202400094"],"URL":"https:\/\/doi.org\/10.1002\/tcr.202400094","archive":["Portico"],"relation":{},"ISSN":["1527-8999","1528-0691"],"issn-type":[{"value":"1527-8999","type":"print"},{"value":"1528-0691","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,8]]},"assertion":[{"value":"2024-05-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-08-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202400094"}}