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Fossil fuel overuse damages the environment and raises sustainability concerns. As a resource\u2010rich element, cobalt oxide hybrids have attracted considerable attention as low\u2010priced and eco\u2010friendly electrocatalysts. Alkaline solutions disperse Co<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> easily despite its highly stable nature, which arises from the reverse spinel structures of Co. Metal oxides, nickel foam, polymeric frameworks, and carbon nanotubes have been successfully served to combine with the Co<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> constructions for improving the electrocatalytic performance. To date, no comprehensive study has systematically investigated the relation between the cobalt oxide hybrid's physicochemical\u2010electronic aspects and its catalytic features. This review mainly focuses on material design, fabrication, morphology, structural characteristics, and electroactivity, considering the critical factors towards practical applications. The economic impacts of the constructions and their expected contribution to large\u2010scale utilizations are also demonstrated. Moreover, this research discusses the synergistic effects of crucial electrochemical parameters on sustainable energy production over the Co<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>\u2010based hybrids. Finally, some beneficial conclusive suggestions are made based on emerging factors for real\u2010world application. 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