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With the synthesis of complex substituted allylboronates, allylboronic acids and allyltrifluoroborates, the type of reactions and the variety of substrates are greatly expanded. Therefore, this review article will emphasize on the aspect of regio\u2010 and stereoselectivity when substituted allylboron species involving and their application on the construction of versatile organic building blocks, drugs and natural products.<\/jats:p>","DOI":"10.1002\/tcr.202400208","type":"journal-article","created":{"date-parts":[[2024,12,21]],"date-time":"2024-12-21T06:45:38Z","timestamp":1734763538000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Recent Progress of Substituted Allylboron Compounds in Catalytic Asymmetric Allylation Reactions"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-2494-5306","authenticated-orcid":false,"given":"Xiaoxue","family":"Tang","sequence":"first","affiliation":[{"name":"Department of Pharmacy The Second Affiliated Hospital of Army Medical University  Chongqing 400037 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yushuang","family":"Chen","sequence":"additional","affiliation":[{"name":"Dr. Yushuang Chen School of Chemistry and Chemical Engineering Chongqing University of Science and Technology  Chongqing 401331 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingbin","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Pharmacy The Second Affiliated Hospital of Army Medical University  Chongqing 400037 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,20]]},"reference":[{"key":"e_1_2_10_1_1","unstructured":"\u00a0"},{"key":"e_1_2_10_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400008h"},{"key":"e_1_2_10_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7NJ02799K"},{"key":"e_1_2_10_4_1","unstructured":"\u00a0"},{"key":"e_1_2_10_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar800170y"},{"key":"e_1_2_10_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr1004474"},{"key":"e_1_2_10_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00362"},{"key":"e_1_2_10_8_1","volume-title":"Allylboration of Carbonyl Compounds","author":"Hall D. 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