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Alongside these intrinsic features, recent advancements in surface functionalization, heterostructure design, and transition\u2010metal hybridization have significantly enhanced their catalytic efficiency for vital energy\u2010related reactions, including the hydrogen evolution reaction, oxygen evolution reaction, carbon dioxide reduction reaction, and oxygen reduction reaction. This review offers a critical examination of the latest strategies that extend beyond traditional MXene applications, with a particular focus on their incorporation into rechargeable zinc\u2013air batteries. We highlight how functional group engineering, interlayer spacing modulation, and lattice strain control influence catalytic performance and reaction kinetics. Despite these advancements, MXenes still face challenges such as structural instability, surface termination heterogeneity, and limited defect control during scalable synthesis. We conclude by discussing emerging solutions, including Janus\u2010type surface patterning and defect engineering, as future directions to guide the strategic development of highly efficient MXene\u2010based electrocatalysts.<\/jats:p>","DOI":"10.1002\/tcr.202500241","type":"journal-article","created":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T14:23:41Z","timestamp":1767882221000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["MXene\u2010Driven Frameworks: Unlocking New Frontiers in Electrocatalysis and Zinc\u2013Air Battery Applications"],"prefix":"10.1002","volume":"26","author":[{"given":"Kanwal","family":"Iqbal","sequence":"first","affiliation":[{"name":"Zhejiang Engineering Laboratory for Green Syntheses and Applications of Fluorine\u2010Containing Specialty Chemicals Institute of Advanced Fluorine\u2010Containing Materials Zhejiang Normal University  Jinhua P. R. 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