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Among the available approaches, photocatalysis, a solar\u2010driven process, has emerged as a particularly promising strategy for applications such as water purification, air pollution control, and carbon dioxide reduction. Within this context, three\u2010dimensional (3D) metal\u2010organic frameworks (MOFs) have attracted significant research interest owing to their distinctive structural characteristics, tunable electronic properties, high porosity, and large surface area. This review provides a comprehensive examination of 3D MOF\u2010based photocatalysts, with a focus on structural design principles, fundamental photocatalytic mechanisms, and their diverse environmental remediation. 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