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Among them, benzodiazines, containing a benzene ring fused with a six\u2010membered diazine containing both nitrogen atoms in the same ring, are of particular significance. Their structural compactness, synthetic versatility, and favorable physicochemical characteristics render them valuable as drug candidates, chemical probes, and intermediates in organic synthesis. Representative members of this class are cinnoline, phthalazine, quinazoline, and quinoxaline that exhibit numerous pharmacological properties, namely anticancer, antimicrobial, anti\u2010inflammatory, anticonvulsant, antimalarial, antioxidant, antihypertensive, and other activities. Although the synthesis of each scaffold has been reviewed individually in the literature, benzodiazines as a broader class remain comparatively underexplored. The present work summarizes recent developments in the synthesis of benzodiazines, with emphasis on methodologies utilizing diverse catalysts such as solid acid catalysts, nanocatalysts, transition\u2010metal catalysts, and ionic liquid\u2010based catalysts. These strategies commonly employ precursors including 2\u2010nitrobenzyl alcohols, 2\u2010alkynylanilines,\n                    <jats:italic>o<\/jats:italic>\n                    \u2010phenylenediamines, and\n                    <jats:italic>o<\/jats:italic>\n                    \u2010alkyl benzophenones, which react with benzylamines, nitrosoarenes, 1,2\u2010dicarbonyls, and di\u2010\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butyl azodicarboxylate, respectively. This overview aims to stimulate further exploration in the synthesis and applications of benzodiazines.\n                  <\/jats:p>","DOI":"10.1002\/tcr.202500308","type":"journal-article","created":{"date-parts":[[2026,2,11]],"date-time":"2026-02-11T06:55:22Z","timestamp":1770792922000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["An Overview on the Catalytic Strategies for the Synthesis of Benzodiazines"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-7936-514X","authenticated-orcid":false,"given":"Hemant Kumar","family":"Rundla","sequence":"first","affiliation":[{"name":"Department of Chemistry Mohanlal Sukhadia University  Udaipur Rajasthan India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-5884-215X","authenticated-orcid":false,"given":"Sunita","family":"Teli","sequence":"additional","affiliation":[{"name":"Department of Chemistry Mohanlal Sukhadia University  Udaipur Rajasthan India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-2189-7659","authenticated-orcid":false,"given":"Shivani","family":"Soni","sequence":"additional","affiliation":[{"name":"Department of Chemistry Mohanlal Sukhadia University  Udaipur Rajasthan India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2946-0409","authenticated-orcid":false,"given":"Shikha","family":"Agarwal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Mohanlal Sukhadia University  Udaipur Rajasthan India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2731-3328","authenticated-orcid":false,"given":"Lokesh Kumar","family":"Agarwal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Mohanlal Sukhadia University  Udaipur Rajasthan India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2026,2,10]]},"reference":[{"key":"e_1_2_11_2_1","first-page":"141","article-title":"A Review: Biological Importance of Heterocyclic Compounds","volume":"9","author":"Al\u2010Mulla A.","year":"2017","journal-title":"Der Pharma Chemica"},{"key":"e_1_2_11_3_1","volume-title":"Heterocyclic Chemistry","author":"Bansal R. 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