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Although hydrogen production via water electrolysis holds great promise, the oxygen evolution reaction (OER) at the anode suffers from slow reaction kinetics, high energy consumption, and the generation of low\u2010value products. By replacing the OER with the alcohol oxidation reaction (AOR), which is thermodynamically more favorable, it is possible to simultaneously produce hydrogen with lower energy consumption and high\u2010value\u2010added chemical products. Spinel oxides exhibit significant potential in these electrocatalytic reactions due to their flexible composition, structural stability, and low cost. This article provides an overview of the crystal structures, preparation methods, and performance enhancement strategies for nanostructured spinel oxides. It then highlights recent advances in OER and AOR (particularly with methanol, ethylene glycol, and glycerol), with a focus on analyzing reaction mechanisms and structure\u2013activity relationships. 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