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Excellent regioselectivity, functional group tolerance, and broad range of substrates are the main advantages of electrochemical difunctionalization reactions. Alkenes and alkynes readily accept radical or ionic derivatives which makes it vital precursors for the electrochemical synthesis of industrially relevant and biologically active molecules through difunctionalization. The integration of cobalt catalysis with electrochemistry not only enhances efficiency and selectivity but also provides a platform for discovering novel transformations, positioning cobalt electrosynergistic catalysis as a transformative tool for precision synthesis of functionalized alkenes and alkynes. Herein, we discuss the recent development in the difunctionalization of alkenes and alkynes via cobalt electrocatalysis.<\/jats:p>","DOI":"10.1002\/tcr.70201","type":"journal-article","created":{"date-parts":[[2026,6,21]],"date-time":"2026-06-21T16:19:53Z","timestamp":1782058793000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrochemical Cobalt\u2010Catalyzed Difunctionalization of Alkenes and Alkynes: Recent Advances in Synthetic Applications"],"prefix":"10.1002","volume":"26","author":[{"given":"Ying\u2010Chun","family":"Song","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology Qingdao Key Laboratory of Biomacromolecular Drug Discovery and Development, College of Chemical Engineering Qingdao University of Science and Technology  Qingdao 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