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Transition\u2010metal complexes play a crucial role in these systems by facilitating electron\u2010transfer and energy\u2010transfer (EnT) processes, thereby enhancing reaction efficiency and selectivity. Among the numerous transformations accessible through photocatalysis, decarboxylative cross\u2010coupling reactions have emerged as a versatile and efficient tool for the construction of carbon\u2013carbon and carbon\u2013heteroatom bonds, utilizing abundant and stable carboxylic acids as readily available coupling partners. In this review, we critically examined recent advances in visible\u2010light\u2010induced decarboxylative cross\u2010coupling reactions from a coordination\u2010chemistry perspective. Key classes of photocatalysts, including ruthenium\u2010, iridium\u2010, copper\u2010, and nickel\u2010based complexes, are discussed alongside cooperative dual\u2010catalytic systems, metallaphotoredox strategies, and metal\u2010free approaches. Emphasis is placed on the mechanistic pathways governing these transformations, including single\u2010electron transfer, ligand\u2010to\u2010metal charge transfer, and EnT processes. 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