{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T16:17:13Z","timestamp":1789489033986,"version":"build-2803163510"},"reference-count":119,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["The Chemical Record"],"abstract":"<jats:p>\n                    Metal oxytellurides (MOTs), a new class of mixed\u2010anion oxychalcogenides with both O\n                    <jats:sup>2\u2212<\/jats:sup>\n                    and Te\n                    <jats:sup>2\u2212<\/jats:sup>\n                    ions, provide a highly tunable platform for next\u2010generation electronic and energy devices. The structural chemistry of MOTs consists of the hard covalent oxide network with soft, polarizable telluride sublattice resulting in tunable electronic structures, adaptable coordination, and enhanced spin\u2013orbit coupling. This Account aims to synthesize the structure\u2013property relationships in MOTs with a unifying theme of how small deviations in anion order, composition, defect chemistry, and coordinated state can dramatically affect band structure, electron\/hole transport, thermal transport, and electrochemical properties. Synthesis discussions focus on the importance of leveraging solid\u2010state, flux\u2010mediated, microwave\u2010assisted, high\u2010pressure, and topochemical transformations for phase stabilization, defect engineering, and particle\/morphology control. The typical bandgap range across MOT families varies between \u223c0.14 and 5.5\u2009eV, and the highest reported thermoelectric figure of merit is ZT\u2009\u2248\u20091.06 for Te\u2010substituted BiCuOTe. Structural models are analyzed with computational analysis, using density functional theory, giving insight into phase stability, defect preferences, and the consequent electronic structure evolutions. Guided by these models, descriptors, and computational predictions, select future directions are suggested for large\u2010scale manufacture, compositional space exploration, property optimization, and commercialization of MOTs for thermoelectric, electrochemical, and optoelectronic devices.\n                  <\/jats:p>","DOI":"10.1002\/tcr.70251","type":"journal-article","created":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T15:56:33Z","timestamp":1789487793000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis\u2010Driven Structure\u2013Property Correlations in Metal Oxytellurides for Emerging Device Applications"],"prefix":"10.1002","author":[{"given":"Prabhukrupa Chinmay","family":"Kumar","sequence":"first","affiliation":[{"name":"Department of Engineering and Materials Physics Institute of Chemical Technology\u2010Indian Oil Odisha Campus  Bhubaneswar 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