{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T00:02:58Z","timestamp":1791504178510,"version":"4.3.4"},"reference-count":81,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2021,11,8]],"date-time":"2021-11-08T00:00:00Z","timestamp":1636329600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Water Environment Research"],"published-print":{"date-parts":[[2021,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:sec><jats:label\/><jats:p>Carbonyl sulfide (COS) and carbon disulfide (CS<jats:sub>2<\/jats:sub>) are important atmospheric gases photochemically generated from organic sulfur precursors in sunlit natural waters. This study examined these processes by evaluating COS and CS<jats:sub>2<\/jats:sub> photoproduction from dimethyl sulfide (DMS) in the presence of dissolved organic matter (DOM). DOM was added because it photochemically produces various reactive intermediates (<jats:sup>3<\/jats:sup>CDOM*, <jats:sup>\u2022<\/jats:sup>OH, <jats:sup>1<\/jats:sup>O<jats:sub>2<\/jats:sub>, and H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>) potentially involved in these reaction pathways. DMS\u2010amended synthetic waters at pH\u20098 were varied in terms of their DOM type and concentration, spiked with the <jats:sup>3<\/jats:sup>CDOM* quenching agent, phenol, in certain cases, and subsequently irradiated over varying exposure times. Results indicated that various DOM types ranging from freshwater to open\u2010ocean DOM increased COS but did not alter CS<jats:sub>2<\/jats:sub>, which remained at nondetect levels. DOM type influenced COS only at higher concentrations (20\u2009mg\/L), whereas increasing DOM concentrations proportionally increased COS concentrations for all DOM types. Phenol addition lowered COS formation for reasons that remained unclear because phenol likely quenched <jats:sup>3<\/jats:sup>CDOM* and DMS\u2010derived sulfur\u2010based radicals. Further comparisons with DMS\u2010spiked natural waters and cysteine (CYS)\u2010spiked synthetic and natural waters assessed previously indicated that COS formation from both precursors in natural waters was always greater than in waters containing DOM alone.<\/jats:p><\/jats:sec><jats:sec><jats:title>Practitioner Points<\/jats:title><jats:p>\n<jats:list list-type=\"bullet\">\n<jats:list-item><jats:p>DMS\u2010 and DOM\u2010spiked synthetic waters formed COS but did not form CS<jats:sub>2<\/jats:sub> during sunlight photolysis.<\/jats:p><\/jats:list-item>\n<jats:list-item><jats:p>In DMS\u2010spiked synthetic solutions, DOM type has a limited influence on COS formation whereas DOM concentration has a stronger influence on COS formation.<\/jats:p><\/jats:list-item>\n<jats:list-item><jats:p>COS formation in the DMS\u2010spiked synthetic waters was fairly proportional to the DOC concentration but was generally lower than COS formation in DMS\u2010spiked natural waters.<\/jats:p><\/jats:list-item>\n<\/jats:list><\/jats:p><\/jats:sec>","DOI":"10.1002\/wer.1650","type":"journal-article","created":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T03:56:01Z","timestamp":1633060561000},"page":"2982-2997","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Influence of dissolved organic matter on carbonyl sulfide and carbon disulfide formation from dimethyl sulfide during sunlight photolysis"],"prefix":"10.1002","volume":"93","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0073-7411","authenticated-orcid":false,"given":"Mahsa","family":"Modiri Gharehveran","sequence":"first","affiliation":[{"name":"Lyles School of Civil Engineering Purdue University  West Lafayette Indiana USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0096-9922","authenticated-orcid":false,"given":"Amisha D.","family":"Shah","sequence":"additional","affiliation":[{"name":"Lyles School of Civil Engineering Purdue University  West Lafayette Indiana USA"},{"name":"Division of Environmental and Ecological Engineering Purdue University  West Lafayette Indiana USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,11,8]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1029\/91GB02809"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/0304-4203(90)90059-L"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/2016JC012465"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF00115242"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/jgrg.20068"},{"key":"e_1_2_8_7_1","first-page":"170","volume-title":"Photochemistry of effluent and natural organic matter and photochemical degradation of micropollutants","author":"Bodhipaksha L. 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