{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T15:54:41Z","timestamp":1787586881903,"version":"build-2736575974"},"reference-count":123,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T00:00:00Z","timestamp":1784246400000},"content-version":"vor","delay-in-days":16,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Water Environment Research"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The textile dye industry releases dye\u2010laden effluents that contaminate water, especially those containing Eriochrome Black T (EBT), a commonly employed anionic dye that poses health risks to humans. To address this problem, increasing attention is being paid to the use of abundant, low\u2010cost, and nontoxic bioadsorbents as sustainable alternatives for wastewater treatment. This work assesses the potential of a new nanocomposite adsorbent (MnO:ES) obtained by combining natural calcium carbonate (CaCO\n                    <jats:sub>3<\/jats:sub>\n                    ) derived from eggshells with manganese oxide (MnO) as an active agent to improve its adsorption capacity. A straightforward physical approach was employed to fabricate the MnO:ES through planetary milling conducted at room temperature for 2\u2009h at a rotational speed of 350\u2009rpm. The synthesized MnO:ES was characterized by Fourier transform infrared spectroscopy (FTIR), X\u2010ray diffraction (XRD), and scanning electron microscopy (SEM\/EDX). The MnO:ES nanocomposite was used to efficiently remove EBT from colored water, achieving a removal efficiency of 98% corresponding to a maximum adsorption capacity of 6.6\u2009mg\/g. The optimal conditions were achieved at natural pH, a temperature of 20\u00b0C, a contact time of 30\u2009min, and an initial EBT concentration of 100\u2009mg\/L. The adsorption experiments were performed using 0.75\u2009g of MnO:ES adsorbent composed of 10\u2009wt% MnO and 90\u2009wt% ES. MnO:ES was found to be dispersible, insoluble in water, and highly paramagnetic. The adsorption of the EBT dye followed pseudo\u2010second\u2010order kinetics and the Langmuir isotherm model, and thermodynamic analysis indicated spontaneous adsorption. Furthermore, microbiological analysis indicated a total absence of pathogenic germs, and a total aerobic bacterial count (TABC) of 190\u2009CEU\/mL was observed, which is relatively low for this treated water. The findings indicate that the incorporation of natural CaCO\n                    <jats:sub>3<\/jats:sub>\n                    into a nanocomposite matrix significantly enhances its chemical stability and affinity adsorption efficiency toward target pollutants.\n                  <\/jats:p>","DOI":"10.1002\/wer.70484","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T07:26:41Z","timestamp":1784273201000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["A Novel Nanocomposite Bioadsorbent Derived From Natural CaCO\n                    <sub>3<\/sub>\n                    for the Efficient Adsorption of Toxic Dyes: Synthesis, Characterization, and Application in Wastewater"],"prefix":"10.1002","volume":"98","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0974-4458","authenticated-orcid":false,"given":"Bendaia","family":"Marwa","sequence":"first","affiliation":[{"name":"Materials Physico\u2010Chemistry Laboratory, Science and Technology Faculty Chadli Bendjedid El Tarf University  El Tarf Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mamine","family":"Hadjer","sequence":"additional","affiliation":[{"name":"Laboratory of Physical Chemistry and Biology of Materials Higher Normal School of Technological Education ENSET  Skikda Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Houaidji","family":"Naoual","sequence":"additional","affiliation":[{"name":"Materials Physico\u2010Chemistry Laboratory, Science and Technology Faculty Chadli Bendjedid El Tarf University  El Tarf Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Diaf","family":"Ilhem","sequence":"additional","affiliation":[{"name":"Materials Physico\u2010Chemistry Laboratory, Science and Technology Faculty Chadli Bendjedid El Tarf University  El Tarf Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheloufi","family":"Hadjer","sequence":"additional","affiliation":[{"name":"Materials Physico\u2010Chemistry Laboratory, Science and Technology Faculty Chadli Bendjedid El Tarf University  El Tarf Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-8991-0243","authenticated-orcid":false,"given":"Barbari","family":"Karima","sequence":"additional","affiliation":[{"name":"Environmental Reaserch Center (CRE)  Annaba Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-9563-426X","authenticated-orcid":false,"given":"Bouziane","family":"Mohamed","sequence":"additional","affiliation":[{"name":"Materials Physico\u2010Chemistry Laboratory, Science and Technology Faculty Chadli Bendjedid El Tarf University  El Tarf Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hazourli","family":"Sabir","sequence":"additional","affiliation":[{"name":"Laboratory of Water Treatment and Valorization of Industrial Wastes, Chemistry Department, Faculty of Sciences Badji\u2010Mokhtar University  Annaba Algeria"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,17]]},"reference":[{"key":"e_1_2_9_2_1","first-page":"1","volume-title":"Chapter: Adsorption Processes in Biopolymer Systems: Fundamentals to Practical Applications","author":"Agbovi H. 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