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Compounds <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> are prepared by reaction of the gallium(III) complex [(nacnac)Ga(\u03b7<jats:sup>2<\/jats:sup>\u2010P<jats:sub>4<\/jats:sub>)] (nacnac = CH[CMeN(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)]<jats:sub>2<\/jats:sub>) with bis(anthracene)ferrate(1\u2013) and \u2010cobaltate(1\u2013) salts. The molecular structures of <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> were determined by X\u2010ray crystallography and feature a P<jats:sub>4<\/jats:sub> chain which binds to the transition metal atom via all four P atoms and to the gallium atom via the terminal P atoms. Multinuclear NMR studies on <jats:bold>2<\/jats:bold> suggest that the molecular structure is preserved in solution.<\/jats:p>","DOI":"10.1002\/zaac.201900351","type":"journal-article","created":{"date-parts":[[2020,2,12]],"date-time":"2020-02-12T21:15:14Z","timestamp":1581542114000},"page":"552-557","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Iron\u2010Gallium and Cobalt\u2010Gallium Tetraphosphido Complexes"],"prefix":"10.1002","volume":"646","author":[{"given":"Christoph G. 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