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The contribution of chemically bound chlorides toward increasing the service life of concrete structures is vital as they help in slowing down the chloride diffusion in the concrete thereby delaying reinforcement depassivation. The authors attempt to increase the chloride binding capacity of concrete by adding a small amount of Mg\u2013Al\u2013NO<jats:sub>2<\/jats:sub> layered double hydroxides (LDHs) with the objective to delay reinforcement corrosion and by this to considerably extend the service life of concrete structures situated in harsh environments. This study presents numerical and experimental analysis of the action of LDH in concrete. Formation factor is used to determine the effective chloride diffusion coefficient. In addition, the chloride binding isotherms together with Poisson\u2013Nernst\u2013Planck equations are used to model the chloride ingress. A comparable chloride binding is observed for concrete with and without Mg\u2013Al\u2013NO<jats:sub>2<\/jats:sub>, depicting only a slight chloride uptake by Mg\u2013Al\u2013NO<jats:sub>2<\/jats:sub>. Further investigations are conducted to understand this behavior by studying the stability and chloride entrapping capacity Mg\u2013Al\u2013NO<jats:sub>2<\/jats:sub> in concrete.<\/jats:p><\/jats:sec>","DOI":"10.1002\/adem.202000398","type":"journal-article","created":{"date-parts":[[2020,6,5]],"date-time":"2020-06-05T13:10:29Z","timestamp":1591362629000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Numerical and Experimental Analysis of Self\u2010Protection in Reinforced Concrete due to Application of Mg\u2013Al\u2013NO<sub>2<\/sub> Layered Double Hydroxides"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6488-1167","authenticated-orcid":false,"given":"Zahid Mohammad","family":"Mir","sequence":"first","affiliation":[{"name":"Surface and Coating Technology Institute of Materials Research Helmholtz-Zentrum Geesthacht Centre for Materials and Coastal Research  Max-Planck Str. 1 21502 Geesthacht Germany"}]},{"given":"Alexandre","family":"Bastos","sequence":"additional","affiliation":[{"name":"DEMaC \u2013 Department of Materials and Ceramic Engineering CICECO \u2013 Aveiro Institute of Materials Universidade de Aveiro  3810-193 Aveiro Portugal"}]},{"given":"Celestino","family":"Gomes","sequence":"additional","affiliation":[{"name":"DEMaC \u2013 Department of Materials and Ceramic Engineering CICECO \u2013 Aveiro Institute of Materials Universidade de Aveiro  3810-193 Aveiro Portugal"}]},{"given":"Urs","family":"Mueller","sequence":"additional","affiliation":[{"name":"Infrastructure and Concrete Technology RISE Research Institutes of Sweden  Brinellgatan 4 504 62 Bor\u00e5s Sweden"}]},{"given":"Maria Cruz","family":"Alonso","sequence":"additional","affiliation":[{"name":"CSIC Institute of Construction Science Eduardo Torroja  Serrano Galvache, 4 28033 Madrid Spain"}]},{"given":"Kristina","family":"Villar","sequence":"additional","affiliation":[{"name":"CSIC Institute of Construction Science Eduardo Torroja  Serrano Galvache, 4 28033 Madrid Spain"}]},{"given":"Miguel P.","family":"Rabade","sequence":"additional","affiliation":[{"name":"Infrastructure and Concrete Technology RISE Research Institutes of Sweden  Brinellgatan 4 504 62 Bor\u00e5s Sweden"}]},{"given":"Frederico","family":"Maia","sequence":"additional","affiliation":[{"name":"SmallMaTek LDA  Rua dos Canhas 3810-075 Aveiro Portugal"}]},{"given":"Cl\u00e1udia M.","family":"Rocha","sequence":"additional","affiliation":[{"name":"SmallMaTek LDA  Rua dos Canhas 3810-075 Aveiro Portugal"}]},{"given":"Philippe","family":"Main\u00e7on","sequence":"additional","affiliation":[{"name":"SINTEF Materials and Chemistry  7465 Trondheim Norway"}]},{"given":"Daniel","family":"H\u00f6che","sequence":"additional","affiliation":[{"name":"Surface and Coating Technology Institute of Materials Research Helmholtz-Zentrum Geesthacht Centre for Materials and Coastal Research  Max-Planck Str. 1 21502 Geesthacht Germany"}]},{"given":"Mario G. 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