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Herein, three\u2010component SPEs based on poly(vinylidene fluoride\u2010co\u2010hexafluoropropylene) as a binder, the 1\u2010butyl\u20103\u2010methylimidazolium thiocyanate ionic liquid as an ionic conductive component, and zeolites, to improve SPE ionic conductivity and electrochemical stability, are prepared and characterized. Different zeolite and zeolite\u2010like structures (clinoptilolite, ETS\u20104, and ETS\u201010) are used, and the effect of lithium\u2010ion exchange in their structures is evaluated. A clear influence of the ion exchange process on the crystallinity of the prepared samples is observed, which plays a key role in the conduction mechanisms. The ionic conductivity of the samples at room temperature is of the order of 10<jats:sup>\u22123<\/jats:sup> S\u2009cm<jats:sup>\u22121<\/jats:sup>, making them suitable for battery applications. The assembled batteries show promising results at room temperature, proving that the ion exchange has a positive effect on battery performance. The ion\u2010exchanged clinoptilolite sample presents the best performance at a prolonged cycle number, with an initial discharge capacity of about 130\u2009mAh\u2009g<jats:sup>\u22121<\/jats:sup> at C\/10, and a capacity retention of 70% after 50 cycles. Thus, it is proved that the ion exchange process in microporous silicates represents a suitable strategy to develop high\u2010performance solid\u2010state lithium\u2010ion batteries (LIBs).<\/jats:p><\/jats:sec>","DOI":"10.1002\/adem.202200849","type":"journal-article","created":{"date-parts":[[2022,7,16]],"date-time":"2022-07-16T13:53:06Z","timestamp":1657979586000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Three\u2010Component Solid Polymer Electrolytes Based on Li\u2010Ion Exchanged Microporous Silicates and an Ionic Liquid for Solid\u2010State Batteries"],"prefix":"10.1002","volume":"25","author":[{"given":"Jo\u00e3o C.","family":"Barbosa","sequence":"first","affiliation":[{"name":"Physics Centre of Minho and Porto Universities (CF-UM-UP) University of Minho  Braga 4710-057 Portugal"},{"name":"Laboratory of Physics for Materials and Emergent Technologies LapMET University of Minho  Braga 4710-057 Portugal"},{"name":"Department of Chemistry and CQ-VR University of Tr\u00e1s-os-Montes e Alto Douro  Vila Real 5000-801 Portugal"}]},{"given":"Daniela M.","family":"Correia","sequence":"additional","affiliation":[{"name":"Physics Centre of Minho and Porto Universities (CF-UM-UP) University of Minho  Braga 4710-057 Portugal"},{"name":"Department of Chemistry and CQ-VR University of Tr\u00e1s-os-Montes e Alto Douro  Vila Real 5000-801 Portugal"}]},{"given":"Manuel","family":"Salado","sequence":"additional","affiliation":[{"name":"BCMaterials, Basque Center for Materials, Applications and Nanostructures UPV\/EHU Science Park  Leioa 48940 Spain"}]},{"given":"Renato","family":"Gon\u00e7alves","sequence":"additional","affiliation":[{"name":"Centre of Chemistry University of Minho  Braga 4710-057 Portugal"}]},{"given":"Stanislav","family":"Ferdov","sequence":"additional","affiliation":[{"name":"Physics Centre of Minho and Porto Universities (CF-UM-UP) University of Minho  Braga 4710-057 Portugal"},{"name":"Laboratory of Physics for Materials and Emergent Technologies LapMET University of Minho  Braga 4710-057 Portugal"}]},{"given":"Ver\u00f3nica","family":"de Zea Bermudez","sequence":"additional","affiliation":[{"name":"Department of Chemistry and CQ-VR University of Tr\u00e1s-os-Montes e Alto Douro  Vila Real 5000-801 Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9266-3669","authenticated-orcid":false,"given":"Carlos M.","family":"Costa","sequence":"additional","affiliation":[{"name":"Physics Centre of Minho and Porto Universities (CF-UM-UP) University of Minho  Braga 4710-057 Portugal"},{"name":"Laboratory of Physics for Materials and Emergent Technologies LapMET University of Minho  Braga 4710-057 Portugal"},{"name":"Institute of Science and Innovation for Bio-Sustainability (IB-S) University of Minho  Braga 4710-053 Portugal"}]},{"given":"Senentxu","family":"Lanceros-Mendez","sequence":"additional","affiliation":[{"name":"BCMaterials, Basque Center for Materials, Applications and Nanostructures UPV\/EHU Science Park  Leioa 48940 Spain"},{"name":"Ikerbasque, Basque Foundation for Science  Bilbao 48009 Spain"}]}],"member":"311","published-online":{"date-parts":[[2022,7,24]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ecolecon.2020.106760"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz5026273"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2016.04.006"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0336-z"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.psep.2011.06.022"},{"key":"e_1_2_8_6_1","first-page":"131","volume-title":"Fast Ion Transport in Solids: Electrodes and Electrolytes","author":"Armand M. 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