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There is demand for a model that provides a vivid and more precise evaluation of the electrical conduction mechanism in these polymers \u2013 especially when they act as hosts to guest species, such as acid dopant ions and nanoparticles. If, for example, the motional behavior of a host\u2013guest organic conducting polymer structure, as related to dynamic stability, is either asynchronous or synchronous, is this reflected in the mechanism of electrical conduction and does it account for the pace of material's degradation? Here, we demonstrate that the answer is affirmative: asynchronous structural motions arising due to loosely bound or free guest species within the host polymer lead to anomalous electrical conduction mechanisms, increased fragility and short lifetime, at odds with the synchronous behavior.<\/jats:p>","DOI":"10.1002\/adfm.201002185","type":"journal-article","created":{"date-parts":[[2011,4,26]],"date-time":"2011-04-26T05:22:37Z","timestamp":1303795357000},"page":"2240-2250","source":"Crossref","is-referenced-by-count":4,"title":["Dynamic Stability of Organic Conducting Polymers and Its Replication in Electrical Conduction and Degradation Mechanisms"],"prefix":"10.1002","volume":"21","author":[{"given":"Emmanuel F. 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