{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,21]],"date-time":"2026-04-21T20:34:57Z","timestamp":1776803697556,"version":"3.51.2"},"reference-count":54,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2012,6,19]],"date-time":"2012-06-19T00:00:00Z","timestamp":1340064000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Adv Funct Materials"],"published-print":{"date-parts":[[2012,10,23]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A simple one\u2010pot approach based on the \u201cbenzyl alcohol route\u201d is used for the preparation of benzoate\u2010 and biphenolate\u2010capped zirconia and, benzoate\u2010capped Eu\u2010doped zirconia nanoparticles. Powder X\u2010ray diffraction studies and high\u2010 resolution transmission electron microscopy (HR\u2010TEM) showed that the nanoparticles present high crystallinity and uniform particle sizes ranging from 3 to 4 nm. FT\u2010IR and solid state NMR (SS\u2010NMR) studies revealed that the nanoparticles are coated with a large amount of organic species when the reaction temperature is above 300 \u00b0C. It was found that the alcohol used as solvent is oxidized at the surface of the nanoparticles to the respective carboxylic acid which acts as a stabilizer, controlling the nanoparticles growth. The optical properties of these hybrid nanoparticles were studied by room and low (12K) temperature photoluminescence spectroscopy, time\u2010resolved spectroscopy and absolute emission quantum yield. The as\u2010synthesized benzoate\u2010 and biphenolate\u2010capped nanoparticles exhibit interesting emission properties in the UV and blue spectral regions together with values of emission quantum yields much higher than those reported for zirconia nanoparticles of similar size. The photoluminescent properties were attributed to a cooperative effect of the capping ligands and the defects associated to the ZrO<jats:sub>2<\/jats:sub> nanoparticles. Due to the overlapping of the various emission components involved (i.e., the emission of europium(III) intra\u20104f<jats:sup>6<\/jats:sup> transitions, defects in the zirconia and capping ligands) a tunable emission color ranging from purplish\u2010pink to greenish\u2010blue could be obtained for the europium\u2010doped zirconia nanoparticles by simply selecting different excitation wavelengths.<\/jats:p>","DOI":"10.1002\/adfm.201200759","type":"journal-article","created":{"date-parts":[[2012,6,19]],"date-time":"2012-06-19T04:21:11Z","timestamp":1340079671000},"page":"4275-4283","source":"Crossref","is-referenced-by-count":44,"title":["One\u2010Step Synthesis and Optical Properties of Benzoate\u2010 and Biphenolate\u2010Capped ZrO<sub>2<\/sub> Nanoparticles"],"prefix":"10.1002","volume":"22","author":[{"given":"Xue","family":"Bai","sequence":"first","affiliation":[]},{"given":"Andrea","family":"Pucci","sequence":"additional","affiliation":[]},{"given":"Vania T.","family":"Freitas","sequence":"additional","affiliation":[]},{"given":"Rute A. S.","family":"Ferreira","sequence":"additional","affiliation":[]},{"given":"Nicola","family":"Pinna","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2012,6,19]]},"reference":[{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1204090"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2011.43"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1191137"},{"key":"e_1_2_7_4_2","volume":"176","author":"Adamski A.","year":"2011","journal-title":"Catal. Today"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.07.009"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(03)00542-9"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac050791t"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2005.05.065"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200801835"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0612145"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1116\/1.591472"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/la980083l"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.200700075"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200902658"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/la900146y"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic025532q"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp8103497"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00339-005-3238-9"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/pssc.200673850"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp111367k"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2039419"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1108712"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3727\/43\/35\/354002"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1512825"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1023\/B:NANO.0000034624.56366.ac"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/app.34688"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200300389"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.physleta.2005.10.035"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704541"},{"key":"e_1_2_7_29_3","doi-asserted-by":"publisher","DOI":"10.1021\/ar600035e"},{"key":"e_1_2_7_29_4","doi-asserted-by":"publisher","DOI":"10.1002\/smll.200400014"},{"key":"e_1_2_7_29_5","doi-asserted-by":"publisher","DOI":"10.1021\/cm060705l"},{"key":"e_1_2_7_29_6","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200601142"},{"key":"e_1_2_7_29_7","doi-asserted-by":"publisher","DOI":"10.1039\/B702854G"},{"key":"e_1_2_7_29_8","doi-asserted-by":"publisher","DOI":"10.1021\/jp9029375"},{"key":"e_1_2_7_29_9","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.200600317"},{"key":"e_1_2_7_29_10","doi-asserted-by":"publisher","DOI":"10.1021\/jp0672609"},{"key":"e_1_2_7_29_11","doi-asserted-by":"publisher","DOI":"10.1021\/nn3010735"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1386-1425(99)00154-7"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1001-0742(07)60073-4"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/b604213a"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/la991273e"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja034258b"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp21987a"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.64.224108"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2852(72)90208-1"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1674897"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100406a018"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.2219399"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.73.235318"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1773154"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/la300288j"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssc.2010.09.025"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-79017-1"}],"container-title":["Advanced Functional Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fadfm.201200759","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adfm.201200759","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T15:41:09Z","timestamp":1759765269000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adfm.201200759"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,6,19]]},"references-count":54,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2012,10,23]]}},"alternative-id":["10.1002\/adfm.201200759"],"URL":"https:\/\/doi.org\/10.1002\/adfm.201200759","archive":["Portico"],"relation":{},"ISSN":["1616-301X","1616-3028"],"issn-type":[{"value":"1616-301X","type":"print"},{"value":"1616-3028","type":"electronic"}],"subject":[],"published":{"date-parts":[[2012,6,19]]}}}