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These functionalized magnetic materials prove to be efficient bioinspired oxidation catalysts of olefins and thiols, using molecular oxygen as oxidant, in total absence of reductants and solvents, with the highest TON (turnover number) yet achieved for this reaction (\u2248200 000). A comparative study between homogeneous and heterogeneous oxidation of cyclohexene is discussed, revealing the heterogeneous system to be the most promising concerning stability and reusability of the catalysts. The full characterization of the magnetic hybrid porphyrinic nanomaterials, by transmission electron microscopy, flame atomic absorption spectrometry, thermogravimetry, N<jats:sub>2<\/jats:sub> sorption, and infrared spectroscopy, is also described.<\/jats:p>","DOI":"10.1002\/adfm.201505405","type":"journal-article","created":{"date-parts":[[2016,2,12]],"date-time":"2016-02-12T10:43:30Z","timestamp":1455273810000},"page":"3359-3368","source":"Crossref","is-referenced-by-count":33,"title":["Biologically Inspired and Magnetically Recoverable Copper Porphyrinic Catalysts: A Greener Approach for Oxidation of Hydrocarbons with Molecular Oxygen"],"prefix":"10.1002","volume":"26","author":[{"given":"C\u00e9sar A.","family":"Henriques","sequence":"first","affiliation":[{"name":"CQC Department of Chemistry University of Coimbra  Rua Larga 3004\u2010535 Coimbra Portugal"}]},{"given":"Auguste","family":"Fernandes","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. Rovisco Pais 1049\u2010001 Lisboa Portugal"}]},{"given":"Liane M.","family":"Rossi","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental Instituto de Qu\u00edmica Universidade de S\u00e3o Paulo  Av. Prof. Lineu Prestes 748 sl. 1256 05508\u2010000 S\u00e3o Paulo SP Brasil"}]},{"given":"M. Filipa","family":"Ribeiro","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. Rovisco Pais 1049\u2010001 Lisboa Portugal"}]},{"given":"M\u00e1rio J. 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