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In this work, the characteristics of the hybrid ZnO\u2010Bi<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> and ZnO\u2010Zn<jats:sub>2<\/jats:sub>SnO<jats:sub>4<\/jats:sub> tetrapod (T) networks are investigated in detail. The gas sensing studies reveal improved performance of the hybrid networks compared to pure ZnO\u2010T networks. For the ZnO\u2010T\u2010Bi<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> networks, an enhancement in H<jats:sub>2<\/jats:sub> gas response is obtained, although the observed p\u2010type sensing behavior is attributed to the formed junctions between the arms of ZnO\u2010T covered with Bi<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> and the modulation of the regions where holes accumulate under exposure to H<jats:sub>2<\/jats:sub> gas. In ZnO\u2010T\u2010Zn<jats:sub>2<\/jats:sub>SnO<jats:sub>4<\/jats:sub> networks, a change in selectivity to CO gas with high response is noted. The devices based on individual ZnO\u2010T\u2010Bi<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> and ZnO\u2010T\u2010Zn<jats:sub>2<\/jats:sub>SnO<jats:sub>4<\/jats:sub> structures showed an enhanced H<jats:sub>2<\/jats:sub> gas response, which is explained on the basis of interactions (electronic sensitization) between the ZnO\u2010T arm and Bi<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> shell layer and single Schottky contact structure, respectively. Density functional theory\u2010based calculations provide mechanistic insights into the interaction of H<jats:sub>2<\/jats:sub> and CO gas molecules with Bi\u2010 and Sn\u2010doped ZnO(0001) surfaces, revealing changes in the Fermi energies, as well as charge transfer between the molecules and surface species, which facilitate gas sensing.<\/jats:p>","DOI":"10.1002\/adfm.201604676","type":"journal-article","created":{"date-parts":[[2016,12,30]],"date-time":"2016-12-30T06:04:00Z","timestamp":1483077840000},"source":"Crossref","is-referenced-by-count":161,"title":["Multifunctional Materials: A Case Study of the Effects of Metal Doping on ZnO Tetrapods with Bismuth and Tin Oxides"],"prefix":"10.1002","volume":"27","author":[{"given":"Vasile","family":"Postica","sequence":"first","affiliation":[{"name":"Department of Microelectronics and Biomedical Engineering Technical University of Moldova  168 Stefan cel Mare Av. 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