{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T20:56:08Z","timestamp":1777323368069,"version":"3.51.4"},"reference-count":48,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2025,5,24]],"date-time":"2025-05-24T00:00:00Z","timestamp":1748044800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Adv Funct Materials"],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Concrete, the world's second most utilized material after water, is responsible for 8% of global greenhouse emissions. Current carbon capturing and storage (CCS) concrete often involves convoluted processes, slow kinetics, limited CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake, non\u2010uniform carbonation in structures, and high cost. Efforts to enhance carbon sequestration often rely on increasing porosities, which compromise the mechanical strength of the resulting concrete. The 3D printing of CCS concrete is reported by incorporating diatomaceous earth (DE), a highly accessible biomineral with hierarchical porosity, into triply periodic minimal surface (TPMS) structures. DE enables stable extrusion, high print fidelity, and reduced density, which are crucial for 3D concrete printing. Further, DE facilitates CaCO\n                    <jats:sub>3<\/jats:sub>\n                    nucleation within the concrete and mitigates carbonation resistance, achieving a maximum CO\n                    <jats:sub>2<\/jats:sub>\n                    absorption of 488.7 gCO\n                    <jats:sub>2<\/jats:sub>\n                    per kg cement in 7 days, a 142% increase over conventional concrete. Optimizing TPMS geometry further enhances carbonation efficiency by enabling uniform CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake throughout the structure. This geometry refinement reduces material usage by 78% and increases the surface\u2010area\u2010to\u2010volume ratio by 515%, leading to a 30% higher CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake while preserving mechanical integrity. The material strategy, together with the optimized concrete printing of TPMS structures, offers a pathway toward scalable and sustainable solutions without undermining concrete's structural functions.\n                  <\/jats:p>","DOI":"10.1002\/adfm.202509259","type":"journal-article","created":{"date-parts":[[2025,5,24]],"date-time":"2025-05-24T15:59:31Z","timestamp":1748102371000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["3D Concrete Printing of Triply Periodic Minimum Surfaces for Enhanced Carbon Capture and Storage"],"prefix":"10.1002","volume":"35","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2306-1175","authenticated-orcid":false,"given":"Kun\u2010Hao","family":"Yu","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering University of Pennsylvania  3231 Walnut Street Philadelphia PA 19104 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6460-7109","authenticated-orcid":false,"given":"Teng","family":"Teng","sequence":"additional","affiliation":[{"name":"Polyhedral Structures Laboratory Department of Architecture University of Pennsylvania  3401 Grays Ferry Avenue Philadelphia PA 19146 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1564-201X","authenticated-orcid":false,"given":"So Hee","family":"Nah","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering University of Pennsylvania  3231 Walnut Street Philadelphia PA 19104 USA"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-1276-7705","authenticated-orcid":false,"given":"Hua","family":"Chai","sequence":"additional","affiliation":[{"name":"Polyhedral Structures Laboratory Department of Architecture University of Pennsylvania  3401 Grays Ferry Avenue Philadelphia PA 19146 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1654-4865","authenticated-orcid":false,"given":"Yefan","family":"Zhi","sequence":"additional","affiliation":[{"name":"Polyhedral Structures Laboratory Department of Architecture University of Pennsylvania  3401 Grays Ferry Avenue Philadelphia PA 19146 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8982-0547","authenticated-orcid":false,"given":"Kun\u2010Yu","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering University of Pennsylvania  3231 Walnut Street Philadelphia PA 19104 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2674-721X","authenticated-orcid":false,"given":"Yinding","family":"Chi","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering University of Pennsylvania  3231 Walnut Street Philadelphia PA 19104 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5302-3412","authenticated-orcid":false,"given":"Peter","family":"Psarras","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Pennsylvania  220 S. 33rd Street Philadelphia PA 19104 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6402-615X","authenticated-orcid":false,"given":"Masoud","family":"Akbarzadeh","sequence":"additional","affiliation":[{"name":"Polyhedral Structures Laboratory Department of Architecture University of Pennsylvania  3401 Grays Ferry Avenue Philadelphia PA 19146 USA"},{"name":"General Robotic, Automation, Sensing and Perception (GRASP) Lab School of Engineering and Applied Science University of Pennsylvania  Philadelphia PA 19104 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8834-3320","authenticated-orcid":false,"given":"Shu","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering University of Pennsylvania  3231 Walnut Street Philadelphia PA 19104 USA"}]}],"member":"311","published-online":{"date-parts":[[2025,5,24]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/d41586-022-00758-4"},{"key":"e_1_2_9_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1364-3"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/d41586-021-02612-5"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adu7379"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adq8594"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00035H"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cemconres.2018.03.015"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-21148-w"},{"key":"e_1_2_9_6_2","doi-asserted-by":"publisher","DOI":"10.3389\/fenrg.2017.00017"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2020.101428"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-8846(01)00498-7"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-01054-8"},{"key":"e_1_2_9_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaa8075"},{"key":"e_1_2_9_8_3","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00075B"},{"key":"e_1_2_9_8_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.conbuildmat.2022.128715"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-8846(01)00490-2"},{"key":"e_1_2_9_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2017.05.014"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.2307\/jj.11374766.40"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201705708"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.143567"},{"key":"e_1_2_9_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2024.143522"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2206684119"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1088\/2631-7990\/ac5be6"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.154674"},{"key":"e_1_2_9_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apmt.2024.102407"},{"key":"e_1_2_9_15_3","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE03658D"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cemconcomp.2020.103855"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2018.08.007"},{"key":"e_1_2_9_17_1","volume-title":"Mineral Commodity Summaries","author":"U.S. Geological Survey","year":"2024"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature08057"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1469-8137.2004.01022.x"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2004.04.019"},{"key":"e_1_2_9_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.conbuildmat.2016.05.080"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0958-9465(98)80006-1"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.3390\/jcs5020058"},{"key":"e_1_2_9_23_1","unstructured":"M.Akbarzadeh Doctoral Thesis ETH Zurich (Switzerland)2016 https:\/\/doi.org\/10.3929\/ethz\u2010a\u2010010867338."},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym14214595"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(00)01418-4"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2023.103779"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2022.103036"},{"key":"e_1_2_9_28_1","first-page":"392","volume-title":"Advances in Architectural Geometry in Architectural Geometry","author":"Bernhard M.","year":"2018"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cemconcomp.2022.104641"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cemconres.2018.02.004"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2017.07.003"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b03345"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cemconcomp.2007.08.003"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.conbuildmat.2010.07.002"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/19047"}],"container-title":["Advanced Functional Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adfm.202509259","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,7]],"date-time":"2025-11-07T07:15:42Z","timestamp":1762499742000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adfm.202509259"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,24]]},"references-count":48,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2025,11]]}},"alternative-id":["10.1002\/adfm.202509259"],"URL":"https:\/\/doi.org\/10.1002\/adfm.202509259","archive":["Portico"],"relation":{},"ISSN":["1616-301X","1616-3028"],"issn-type":[{"value":"1616-301X","type":"print"},{"value":"1616-3028","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,24]]},"assertion":[{"value":"2025-04-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2509259"}}