{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T12:26:12Z","timestamp":1787401572846,"version":"3.56.0"},"reference-count":46,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22275015"],"award-info":[{"award-number":["22275015"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22535001"],"award-info":[{"award-number":["22535001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["FRF\u2010IDRY\u2010GD25\u2010002"],"award-info":[{"award-number":["FRF\u2010IDRY\u2010GD25\u2010002"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Adv Funct Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Zero thermal expansion (ZTE) alloys hold great promise for applications in precision instruments, yet are severely limited by intrinsic brittleness and low thermal conductivity. Herein, enabled by optimizing mixing enthalpy, we report on a dual\u2010phase metallic composite that shows ZTE (\u03b1\n                    <jats:sub>l<\/jats:sub>\n                    = +0.6 \u00d7 10\n                    <jats:sup>\u22126<\/jats:sup>\n                    K\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) over a wide temperature range of 200\u2013320 K together with high compressive strength (922\u00a0MPa) and thermal conductivity (23.2 W\u00b7m\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7K\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Strong negative mixing enthalpies stabilize the Fe\u2010based Laves phase with giant room\u2010temperature negative thermal expansion (NTE, \u03b1\n                    <jats:sub>V<\/jats:sub>\n                    = \u221248 \u00d7 10\n                    <jats:sup>\u22126<\/jats:sup>\n                    K\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 280\u2013330 K) in Hf\n                    <jats:sub>0.875<\/jats:sub>\n                    Ta\n                    <jats:sub>0.075<\/jats:sub>\n                    Nb\n                    <jats:sub>0.05<\/jats:sub>\n                    Fe\n                    <jats:sub>2<\/jats:sub>\n                    (HTNF), and positive mixing enthalpy drives phase separation between Cu and HTNF. Neutron powder diffraction reveals that the NTE of the ferromagnetic HTNF originates from the magnetovolume effect driven by substantial variations in local magnetic moments. The ZTE of the composite is achieved by mutual compensation of lattice expansions between the two phases. Coexistence of hard and soft natural dual phases thus yields such high compressive strength. This work gives an effective strategy for achieving ZTE alloys together with good mechanical properties and thermal conductivity.\n                  <\/jats:p>","DOI":"10.1002\/adfm.77876","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T11:53:22Z","timestamp":1787399602000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Mixing Enthalpy Optimized Zero Thermal Expansion With High Compressive Strength and Thermal Conductivity"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-7848-6567","authenticated-orcid":false,"given":"Jian","family":"Li","sequence":"first","affiliation":[{"name":"Institute of Solid State Chemistry State Key Laboratory for Advanced Metals and Materials University of Science and Technology Beijing  Beijing People's Republic of 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