{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T04:47:00Z","timestamp":1791780420326,"version":"4.3.4"},"reference-count":44,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T00:00:00Z","timestamp":1791676800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T00:00:00Z","timestamp":1791676800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22472145"],"award-info":[{"award-number":["22472145"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Adv Funct Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Functional separators that regulate ion transport before lithium ions (Li\n                    <jats:sup>+<\/jats:sup>\n                    ) reach the lithium metal surface are critical for mitigating dendritic deposition and interfacial instability in lithium metal batteries. However, most separator designs mainly emphasize Li\n                    <jats:sup>+<\/jats:sup>\n                    affinity or electrolyte wettability, while the migration and decomposition behavior of anions remains insufficiently controlled. Herein, a coordination\u2010gated anion\u2010sieving separator is developed by constructing a UiO\u201066@F\u2010COF@Ni core\u2013shell interlayer on commercial polypropylene. In this architecture, the UiO\u201066 core provides stable porous transport channels, and the fluorinated imine\u2010linked COF shell creates a polar ion\u2010regulating interface. The introduced Ni\n                    <jats:sup>2+<\/jats:sup>\n                    coordination centers interact with PF\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    to modulate anion migration and interfacial decomposition. Benefiting from the coupled MOF@COF heterointerface and anion\u2010sieving effect, the separator exhibits high ionic conductivity, enhanced Li\n                    <jats:sup>+<\/jats:sup>\n                    transference, and reduced interfacial resistance. The regulated ion flux alleviates concentration polarization, guides uniform Li deposition, and promotes the formation of a compact inorganic\u2010rich SEI. Consequently, LFP||Li batteries retain 126.1\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 1200 cycles at 2.0 C, and high\u2010voltage NCM811||Li batteries maintain 141.4\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 600 cycles at 3.0 C. This coordination\u2010regulated MOF@COF separator provides a practical strategy for stable, high\u2010rate, and high\u2010voltage lithium metal batteries.\n                  <\/jats:p>","DOI":"10.1002\/adfm.78954","type":"journal-article","created":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T04:19:27Z","timestamp":1791778767000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Coordination\u2010Gated MOF@COF Functional Separators for Regulating Ion Flux in Lithium Metal Batteries"],"prefix":"10.1002","author":[{"given":"Kaifu","family":"Xu","sequence":"first","affiliation":[{"name":"School of Chemistry &amp; Materials Yangzhou University  Yangzhou Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingxin","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Materials Yangzhou University  Yangzhou Jiangsu 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