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Currently, they are also gaining attention\u00a0for sodium\u2010ion batteries (SIBs) due to their low volume change and safety. However, their performance in sodium storage remains limited, primarily due to the larger Na\n                    <jats:sup>+<\/jats:sup>\n                    ion radius. Here, for the first time, an iron niobate is reported with a columbite structure as a high\u2010performance sodium storage anode. The presence of iron triggers\u00a0the loss of long\u2010range order through disorder of the FeO\n                    <jats:sub>6<\/jats:sub>\n                    octahedra local structure, subsequently allowing reversible sodium storage in an amorphous phase. Simultaneously, the formation of short\u2010range ordered zigzag\u2010chain structures within the NbO\n                    <jats:sub>6<\/jats:sub>\n                    planes creates a \u201cskeleton\u201d that offers abundant active sites for pseudocapacitive ion storage and enhanced ion diffusion pathways. These characteristics of FeNb\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>6<\/jats:sub>\n                    make it an effective intercalation host, offering high capacity along with fast Na\n                    <jats:sup>+<\/jats:sup>\n                    kinetics, as demonstrated through operando and ex situ characterizations. It leads to an applicable reversible capacity (&gt;300 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) with a favorable average voltage of \u22480.6\u00a0V and excellent rate capability (180.4 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at a current density of 2 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This study provides insights into the development of intrinsically active transition metal oxides for Na\n                    <jats:sup>+<\/jats:sup>\n                    \u2010ion intercalation.\n                  <\/jats:p>","DOI":"10.1002\/adma.202504100","type":"journal-article","created":{"date-parts":[[2025,7,29]],"date-time":"2025-07-29T07:25:51Z","timestamp":1753773951000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["FeNb\n                    <sub>2<\/sub>\n                    O\n                    <sub>6<\/sub>\n                    as a High\u2010Performance Anode for Sodium\u2010Ion Batteries Enabled by Structural Amorphization Coupled with NbO\n                    <sub>6<\/sub>\n                    Local Ordering"],"prefix":"10.1002","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-2031-6968","authenticated-orcid":false,"given":"Yanchen","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry and The Center for the Science of Materials Berlin Humboldt\u2010Universit\u00e4t zu Berlin  Brook\u2010Taylor\u2010Str. 2 12489 Berlin Germany"}]},{"given":"Ana","family":"Guilherme Buzanich","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und \u2010pr\u00fcfung (BAM)  Richard\u2010Willst\u00e4tter\u2010Stra\u00dfe 11 12489 Berlin Germany"}]},{"given":"Paola","family":"Alippi","sequence":"additional","affiliation":[{"name":"CNR\u2010ISM Consiglio Nazionale delle Ricerche Istituto di Struttura della Materia  Via Salaria Km 29.3 Monterotondo Stazione Roma I\u201000015 Italy"}]},{"given":"Luciano A.","family":"Montoro","sequence":"additional","affiliation":[{"name":"Department of Chemistry Universidade Federal de Minas Gerais  Belo Horizonte MG 31270\u2010901 Brazil"}]},{"given":"Kug\u2010Seung","family":"Lee","sequence":"additional","affiliation":[{"name":"PLS\u2010II Beamline Depart. \/ Pohang Accelerator Laboratory POSTECH  80 Jigokro\u2010127\u2010beongil Nam\u2010gu Pohang Gyeongbuk 37673 South Korea"}]},{"given":"Taeyeol","family":"Jeon","sequence":"additional","affiliation":[{"name":"PLS\u2010II Beamline Depart. \/ Pohang Accelerator Laboratory POSTECH  80 Jigokro\u2010127\u2010beongil Nam\u2010gu Pohang Gyeongbuk 37673 South Korea"}]},{"given":"Kilian","family":"Wei\u00dfer","sequence":"additional","affiliation":[{"name":"Department of Chemistry and The Center for the Science of Materials Berlin Humboldt\u2010Universit\u00e4t zu Berlin  Brook\u2010Taylor\u2010Str. 2 12489 Berlin Germany"}]},{"given":"Martin A.","family":"Karlsen","sequence":"additional","affiliation":[{"name":"Deutsches Elektronen\u2010Synchrotron DESY Notkestr. 85 22607 Hamburg Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1082-2302","authenticated-orcid":false,"given":"Patr\u00edcia A.","family":"Russo","sequence":"additional","affiliation":[{"name":"Department of Chemistry and The Center for the Science of Materials Berlin Humboldt\u2010Universit\u00e4t zu Berlin  Brook\u2010Taylor\u2010Str. 2 12489 Berlin Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1273-803X","authenticated-orcid":false,"given":"Nicola","family":"Pinna","sequence":"additional","affiliation":[{"name":"Department of Chemistry and The Center for the Science of Materials Berlin Humboldt\u2010Universit\u00e4t zu Berlin  Brook\u2010Taylor\u2010Str. 2 12489 Berlin Germany"}]}],"member":"311","published-online":{"date-parts":[[2025,7,29]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-024-02023-7"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202415611"},{"key":"e_1_2_7_1_3","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00929G"},{"key":"e_1_2_7_2_1","volume":"9","author":"Zhang X.","year":"2019","journal-title":"Adv. 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