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To reach this objective, ternary Z\u2010scheme LaFe<jats:sub>0.5<\/jats:sub>Co<jats:sub>0.5<\/jats:sub>O<jats:sub>3<\/jats:sub>\/Ag<jats:sub>10<\/jats:sub>\/graphitic carbon nitride (LFCO\/Ag<jats:sub>10<\/jats:sub>\/g\u2010CN) heterojunctions with layered structure are designed. The obtained results show that: 1) the Ag nanoparticles (NPs) act as bridges to link LFCO and g\u2010CN, providing a place for recombination of useless electrons and holes; 2) some of the Ag atoms enter the LFCO lattice as Ag<jats:sup>+<\/jats:sup>, but most of them are at the surface in the form of Ag NPs, while g\u2010CN coats the surface of LFCO\/Ag<jats:sub>10<\/jats:sub> as a thin film; 3) LFCO\/Ag<jats:sub>10<\/jats:sub>\/g\u2010CN exhibits improved e<jats:sup>\u2212<\/jats:sup>\/h<jats:sup>+<\/jats:sup> separation efficiency, electron transfer rate, and photocurrent response, compared to g\u2010CN and LFCO\/Ag<jats:sub>10<\/jats:sub> alone. Catalytic tests show that LFCO\/Ag<jats:sub>10<\/jats:sub>\/g\u2010CN is active for photo\u2010Fenton degradation of tetracycline hydrochloride (TC), with 87% TC conversion obtained at 40 min. Mechanistic studies show that \u2022O<jats:sup>2\u2212<\/jats:sup> and \u2022OH radicals are the reactive species of the reaction, and a synergistic effect between light and H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> is produced by generating extra \u2022OH radicals. LFCO\/Ag<jats:sub>10<\/jats:sub>\/g\u2010CN is also highly stable in the reaction conditions, with no appreciable activity loss up to four reuse cycles.<\/jats:p>","DOI":"10.1002\/admi.202101902","type":"journal-article","created":{"date-parts":[[2022,1,15]],"date-time":"2022-01-15T08:29:28Z","timestamp":1642235368000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Construction of Ag\u2010Bridged Z\u2010Scheme LaFe<sub>0.5<\/sub>Co<sub>0.5<\/sub>O<sub>3<\/sub>\/Ag<sub>10<\/sub>\/Graphitic Carbon Nitride Heterojunctions for Photo\u2010Fenton Degradation of Tetracycline Hydrochloride: Interfacial Electron Effect and Reaction Mechanism"],"prefix":"10.1002","volume":"9","author":[{"given":"Xuelian","family":"Xu","sequence":"first","affiliation":[{"name":"Hubei Key Laboratory of Biomass Fibers and Eco\u2010dyeing and Finishing College of Chemistry and Chemical Engineering Wuhan Textile University  Wuhan 430200 P. R. 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China"}]},{"given":"Huiting","family":"Bi","sequence":"additional","affiliation":[{"name":"Hubei Key Laboratory of Biomass Fibers and Eco\u2010dyeing and Finishing College of Chemistry and Chemical Engineering Wuhan Textile University  Wuhan 430200 P. R. China"}]},{"given":"S\u00f3nia A. C.","family":"Carabineiro","sequence":"additional","affiliation":[{"name":"LAQV\u2010REQUIMTE Department of Chemistry NOVA School of Science and Technology Universidade NOVA de Lisboa  Largo da Torre Caparica 2829\u2010516 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