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The effects on the catalytic activity of various factors, e.g., the relative amounts of cyclohexane, oxidant, catalyst, solvent and nitric acid, reaction time, catalyst recycling and impact of both carbon\u2010 and oxygen\u2010centred radical traps (supporting mainly radical mechanisms) were investigated and allowed us to achieve yields and TONs up to <jats:italic>ca.<\/jats:italic> 39% and 380, respectively, corresponding to the most active copper systems so far reported for the oxidation of cyclohexane under mild conditions. The catalysts can be reused for recycling and, at least complex <jats:bold>4<\/jats:bold> maintains almost the same level of activity even after five reaction cycles. The preparation of the new complexes <jats:bold>1, 2b<\/jats:bold> and <jats:bold>2c<\/jats:bold> by self\u2010assembly at room temperature, and their full characterization by IR spectroscopy, FAB\u2010MS<jats:sup>+<\/jats:sup>, elemental and X\u2010ray diffraction structural (for <jats:bold>1<\/jats:bold> and <jats:bold>2c<\/jats:bold>) analyses are also reported.<\/jats:p>","DOI":"10.1002\/adsc.200505216","type":"journal-article","created":{"date-parts":[[2006,1,19]],"date-time":"2006-01-19T02:47:41Z","timestamp":1137638861000},"page":"159-174","source":"Crossref","is-referenced-by-count":166,"title":["Mild Peroxidative Oxidation of Cyclohexane Catalyzed by Mono\u2010, Di\u2010, Tri\u2010, Tetra\u2010 and Polynuclear Copper Triethanolamine Complexes"],"prefix":"10.1002","volume":"348","author":[{"given":"Alexander\u2005M.","family":"Kirillov","sequence":"first","affiliation":[]},{"given":"Maximilian\u2005N.","family":"Kopylovich","sequence":"additional","affiliation":[]},{"given":"Marina\u2005V.","family":"Kirillova","sequence":"additional","affiliation":[]},{"given":"Evgeny\u2005Yu.","family":"Karabach","sequence":"additional","affiliation":[]},{"given":"Matti","family":"Haukka","sequence":"additional","affiliation":[]},{"given":"M.\u2005F\u00e1tima\u2005C.\u2005Guedes","family":"da\u2005Silva","sequence":"additional","affiliation":[]},{"given":"Armando\u2005J.\u2005L.","family":"Pombeiro","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2006,1,19]]},"reference":[{"key":"e_1_2_1_1_2","doi-asserted-by":"crossref","DOI":"10.1093\/hesc\/9780198559177.001.0001","volume-title":"Applied Organometallic Chemistry and Catalysis","author":"Whyman R.","year":"2001"},{"key":"e_1_2_1_2_2","doi-asserted-by":"crossref","DOI":"10.1007\/0-306-46945-6","volume-title":"Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes","author":"Shilov A. 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