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The iron complexes are the most active ones (reaching TON values up to <jats:italic>ca.<\/jats:italic> 690), the effects of a variety of factors are reported and the reaction is shown to proceed <jats:italic>via<\/jats:italic> both C\u2010 and O\u2010centred radical mechanisms, conceivably involving a metal\u2010based oxidant.<\/jats:p>","DOI":"10.1002\/adsc.200700529","type":"journal-article","created":{"date-parts":[[2008,3,17]],"date-time":"2008-03-17T15:25:10Z","timestamp":1205767510000},"page":"706-716","source":"Crossref","is-referenced-by-count":133,"title":["Half\u2010Sandwich Scorpionate Vanadium, Iron and Copper Complexes: Synthesis and Application in the Catalytic Peroxidative Oxidation of Cyclohexane under Mild Conditions"],"prefix":"10.1002","volume":"350","author":[{"given":"Telma F.\u2005S.","family":"Silva","sequence":"first","affiliation":[]},{"given":"Elisabete C.\u2005B.\u2005A.","family":"Alegria","sequence":"additional","affiliation":[]},{"given":"Lu\u00edsa M.\u2005D.\u2005R.\u2005S.","family":"Martins","sequence":"additional","affiliation":[]},{"given":"Armando J.\u2005L.","family":"Pombeiro","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2008,3,18]]},"reference":[{"key":"e_1_2_1_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(04)00131-6"},{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b413121e"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/B0-08-043748-6\/01179-8"},{"key":"e_1_2_1_4_2","doi-asserted-by":"crossref","DOI":"10.1142\/p148","volume-title":"Scorpionates \u2010 The Coordination Chemistry of Poly(pyrazolyl)borate Ligands","author":"Trofimenko S.","year":"1999"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20000717)39:14<2464::AID-ANIE2464>3.0.CO;2-5"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200200604"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2004.11.005"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/b611209a"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.08.017"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619405.ch5b"},{"key":"e_1_2_1_11_2","volume-title":"Organic Reactions Catalyzed by Metal Complexes","author":"Shul\u2019pin G. 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