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High yields (up to 89%) and good to excellent isomer ratios (up to 98:2) were achieved using aryl olefins as starting materials. This new methodology allows the preparation of secondary alcohols, from simple olefins, and paves the way for the synthesis of high\u2010value products, namely vinylindole and anethole derivatives.<\/jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/mcontent.gif\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/adsc.201300968","type":"journal-article","created":{"date-parts":[[2014,3,18]],"date-time":"2014-03-18T17:28:01Z","timestamp":1395163681000},"page":"1223-1228","source":"Crossref","is-referenced-by-count":13,"title":["Rhodium\u2010Catalysed Tandem Hydroformylation\/Arylation Reaction with Boronic Acids"],"prefix":"10.1002","volume":"356","author":[{"given":"Ana R.","family":"Almeida","sequence":"first","affiliation":[]},{"given":"Roberto D.","family":"Dias","sequence":"additional","affiliation":[]},{"given":"Carlos J. 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