{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,1]],"date-time":"2026-05-01T09:06:57Z","timestamp":1777626417692,"version":"3.51.4"},"reference-count":64,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2024,6,27]],"date-time":"2024-06-27T00:00:00Z","timestamp":1719446400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100016218","name":"Ag\u00eancia Regional para o Desenvolvimento da Investiga\u00e7\u00e3o, Tecnologia e Inova\u00e7\u00e3o","doi-asserted-by":"publisher","award":["https:\/\/doi.org\/10.54499\/LA\/P\/0056\/2020"],"award-info":[{"award-number":["https:\/\/doi.org\/10.54499\/LA\/P\/0056\/2020"]}],"id":[{"id":"10.13039\/100016218","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Sustainable Systems"],"published-print":{"date-parts":[[2024,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>This work describes a very efficient methodology for the methanolysis of polyester and polycarbonate plastic waste into a variety of valuable products using homogeneous and heterogeneous manganese compounds in the presence of KO<jats:italic><jats:sup>t<\/jats:sup><\/jats:italic>Bu. Excellent yields are obtained using 1 mol% of the homogeneous catalysts Mn(OTf)<jats:sub>2<\/jats:sub>, Mn<jats:sub>2<\/jats:sub>(CO)<jats:sub>10<\/jats:sub>, MnBr(CO)<jats:sub>5<\/jats:sub>, and MeCpMn(CO)<jats:sub>3<\/jats:sub> and 5 mol% of KO<jats:italic><jats:sup>t<\/jats:sup><\/jats:italic>Bu, under mild reaction conditions. The heterogeneous manganese catalyst, manganese(II) ethyl\/butyl phosphonate silica (Si\u2010Mn), also successfully promoted the methanolysis of polyester and polycarbonate plastic waste with excellent yields. Furthermore, this heterogeneous catalyst can be applied in at least 12 catalytic cycles with excellent yields.<\/jats:p>","DOI":"10.1002\/adsu.202400111","type":"journal-article","created":{"date-parts":[[2024,6,27]],"date-time":"2024-06-27T03:39:38Z","timestamp":1719459578000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Methanolysis of Plastic Waste with Manganese Compounds"],"prefix":"10.1002","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4225-4247","authenticated-orcid":false,"given":"Daniel L.","family":"Louren\u00e7o","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. Rovisco Pais Lisboa 1049\u2010001 Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5919-7723","authenticated-orcid":false,"given":"Ana C.","family":"Fernandes","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. Rovisco Pais Lisboa 1049\u2010001 Portugal"}]}],"member":"311","published-online":{"date-parts":[[2024,6,27]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c01717"},{"key":"e_1_2_8_2_1","first-page":"341","volume-title":"Recent advances in the synthesis of nitrogen compounds from biomass derivatives in: Methodologies in Amine Synthesis. Challenges and Applications","author":"Fernandes A. C.","year":"2020"},{"key":"e_1_2_8_3_1","first-page":"139","volume":"14","author":"Fernandes A. C.","year":"2024","journal-title":"Synthesis Appl. Chem. Mater"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202001955"},{"key":"e_1_2_8_5_1","volume":"4","author":"Sadraei S. I.","year":"2018","journal-title":"Phys. Sci. Rev."},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00486"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8GC00915E"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8GC01343H"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2021.112094"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.05.022"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2019.01.003"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1155\/2018\/2316939"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/c004654j"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.201700807"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.1c03346"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/pi.6555"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-021-00407-8"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2023.118729"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122744"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC01872E"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC03337F"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2MH01549H"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym14153133"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202200522"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00648-4"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100874"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma14174782"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2021.100514"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202101631"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100652"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100752"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202002666"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.17.53"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100904"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202001905"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC01252A"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC01634B"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc00541d"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500907"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aat9669"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b01842"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC00184E"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2GC02186B"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9GC04206G"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal12040381"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2023.113128"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100130"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202300217"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202300381"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202400042"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201810605"},{"key":"e_1_2_8_52_1","first-page":"69","volume-title":"Advances in Chemistry Research","author":"Fernandes A. C.","year":"2019"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal13020421"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsengineeringau.2c00029"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c07203"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c01708"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202104004"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c01207"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201900242"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10924-020-01824-6"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202003389"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0PY00292E"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10924-020-01824-6"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2020.115642"}],"container-title":["Advanced Sustainable Systems"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adsu.202400111","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T11:33:38Z","timestamp":1759750418000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adsu.202400111"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,6,27]]},"references-count":64,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2024,11]]}},"alternative-id":["10.1002\/adsu.202400111"],"URL":"https:\/\/doi.org\/10.1002\/adsu.202400111","archive":["Portico"],"relation":{},"ISSN":["2366-7486","2366-7486"],"issn-type":[{"value":"2366-7486","type":"print"},{"value":"2366-7486","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,6,27]]},"assertion":[{"value":"2024-02-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-06-27","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2400111"}}