{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T23:03:46Z","timestamp":1771455826901,"version":"3.50.1"},"reference-count":31,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2022,6,5]],"date-time":"2022-06-05T00:00:00Z","timestamp":1654387200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2022,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Zeolites and metal\u2010organic frameworks (MOFs) are considered as \u201ccompetitors\u201d for new separation processes. The production of high\u2010quality gasoline is currently achieved through the total isomerization process that separates pentane and hexane isomers while not reaching the ultimate goal of a research octane number (RON) higher than 92. This work demonstrates how a synergistic action of the zeolite 5A and the MIL\u2010160(Al) MOF leads to a novel adsorptive process for octane upgrading of gasoline through an efficient separation of isomers. This innovative mixed\u2010bed adsorbent strategy encompasses a thermodynamically driven separation of hexane isomers according to the degree of branching by MIL\u2010160(Al) coupled to a steric rejection of linear isomers by the molecular sieve zeolite 5A. Their adsorptive separation ability is further evaluated under real conditions by sorption breakthrough and continuous cyclic experiments with a mixed bed of shaped adsorbents. Remarkably, at the industrially relevant temperature of 423 K, an ideal sorption hierarchy of low RON over high RON alkanes is achieved, i.e., <jats:italic>n<\/jats:italic>\u2010hexane \u226b <jats:italic>n<\/jats:italic>\u2010pentane \u226b 2\u2010methylpentane &gt;\u00a03\u2010methylpentane \u22d9 2,3\u2010dimethylbutane &gt; isopentane \u2248 2,2\u2010dimethylbutane, together with a productivity of 1.14\u00a0mol dm<jats:sup>\u22123<\/jats:sup> and a high RON of 92, which is a leap\u2010forward compared with existing processes.<\/jats:p>","DOI":"10.1002\/advs.202201494","type":"journal-article","created":{"date-parts":[[2022,6,5]],"date-time":"2022-06-05T22:00:02Z","timestamp":1654466402000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["Separation of Branched Alkanes Feeds by a Synergistic Action of Zeolite and Metal\u2010Organic Framework"],"prefix":"10.1002","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6488-2001","authenticated-orcid":false,"given":"Pedro F.","family":"Br\u00e2ntuas","sequence":"first","affiliation":[{"name":"Centro de Investiga\u00e7\u00e3o de Montanha (CIMO) Instituto Polit\u00e9cnico de Bragan\u00e7a  Campus de Santa Apol\u00f3nia Bragan\u00e7a 5300\u2010253 Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5227-9790","authenticated-orcid":false,"given":"Adriano","family":"Henrique","sequence":"additional","affiliation":[{"name":"Centro de Investiga\u00e7\u00e3o de Montanha (CIMO) Instituto Polit\u00e9cnico de Bragan\u00e7a  Campus de Santa Apol\u00f3nia Bragan\u00e7a 5300\u2010253 Portugal"},{"name":"LSRE\u2010LCM \u2010 Laboratory of Separation and Reaction Engineering \u2013 Laboratory of Catalysis and Materials Faculty of Engineering University of Porto  Rua Dr. Roberto Frias Porto 4200\u2010465 Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2025-4115","authenticated-orcid":false,"given":"Mohammad","family":"Wahiduzzaman","sequence":"additional","affiliation":[{"name":"ICGM University of Montpellier  CNRS, ENSCM, Montpellier Montpellier 34095 France"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1411-0580","authenticated-orcid":false,"given":"Alexander","family":"von Wedelstedt","sequence":"additional","affiliation":[{"name":"ICGM University of Montpellier  CNRS, ENSCM, Montpellier Montpellier 34095 France"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1901-1060","authenticated-orcid":false,"given":"Tanmoy","family":"Maity","sequence":"additional","affiliation":[{"name":"Centro de Investiga\u00e7\u00e3o de Montanha (CIMO) Instituto Polit\u00e9cnico de Bragan\u00e7a  Campus de Santa Apol\u00f3nia Bragan\u00e7a 5300\u2010253 Portugal"},{"name":"Tata Institute of Fundamental Research\u2010Hyderabad  Hyderabad Telangana 500046 India"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0715-4761","authenticated-orcid":false,"given":"Al\u00edrio E.","family":"Rodrigues","sequence":"additional","affiliation":[{"name":"LSRE\u2010LCM \u2010 Laboratory of Separation and Reaction Engineering \u2013 Laboratory of Catalysis and Materials Faculty of Engineering University of Porto  Rua Dr. Roberto Frias Porto 4200\u2010465 Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2542-6943","authenticated-orcid":false,"given":"Farid","family":"Nouar","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Poreux de Paris ESPCI Paris Ecole Normale Sup\u00e9rieure de Paris CNRS PSL University  Paris 75005 France"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2779-8142","authenticated-orcid":false,"given":"U\u2010Hwang","family":"Lee","sequence":"additional","affiliation":[{"name":"Research Group for Nanocatalysts (RGN) and Chemical and Process Technology Division Korea Research Institute of Chemical Technology (KRICT)  Gajeong\u2010Ro 141 Yuseong Daejeon 34114 Republic of Korea"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6038-0816","authenticated-orcid":false,"given":"Kyung\u2010Ho","family":"Cho","sequence":"additional","affiliation":[{"name":"Research Group for Nanocatalysts (RGN) and Chemical and Process Technology Division Korea Research Institute of Chemical Technology (KRICT)  Gajeong\u2010Ro 141 Yuseong Daejeon 34114 Republic of Korea"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2096-0450","authenticated-orcid":false,"given":"Guillaume","family":"Maurin","sequence":"additional","affiliation":[{"name":"ICGM University of Montpellier  CNRS, ENSCM, Montpellier Montpellier 34095 France"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1778-3833","authenticated-orcid":false,"given":"Jos\u00e9 A. C.","family":"Silva","sequence":"additional","affiliation":[{"name":"Centro de Investiga\u00e7\u00e3o de Montanha (CIMO) Instituto Polit\u00e9cnico de Bragan\u00e7a  Campus de Santa Apol\u00f3nia Bragan\u00e7a 5300\u2010253 Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3040-2564","authenticated-orcid":false,"given":"Christian","family":"Serre","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Poreux de Paris ESPCI Paris Ecole Normale Sup\u00e9rieure de Paris CNRS PSL University  Paris 75005 France"}]}],"member":"311","published-online":{"date-parts":[[2022,6,5]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/532435a"},{"key":"e_1_2_8_2_1","doi-asserted-by":"crossref","unstructured":"T. C.Holcombe U.S. Patent4 210 771 1980.","DOI":"10.2307\/1057074"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01604a001"},{"key":"e_1_2_8_4_1","volume-title":"Handbook of Petroleum Refining Processes","author":"Meyers R. A.","year":"2004"},{"key":"e_1_2_8_5_1","unstructured":"T. C.Holcombe T. C.Sager W. K.Volles A. S.Zarchy U.S. Patent4 929 799 1990."},{"key":"e_1_2_8_6_1","unstructured":"A.Minkkinen L.Mank S.Jullian U.S. Patent52333120 1993."},{"key":"e_1_2_8_7_1","first-page":"28","volume-title":"NPRA Annu. Meet.","author":"Ross J.","year":"2004"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp980674k"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2006.12.011"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.11233"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690480910"},{"key":"e_1_2_8_12_1","first-page":"13","volume":"304","author":"F\u00e9rey G.","year":"2007","journal-title":"L'actualit\u00e9 Chim."},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.05.019"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201601133"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201704303"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00658"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enchem.2021.100057"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1234071"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-04152-5"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA05538G"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201401974"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE00459E"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01769"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1FD00018G"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201502418"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201700164"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.7b08856"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm3025445"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00051a040"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp984742e"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202201494","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.202201494","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202201494","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T10:05:00Z","timestamp":1759745100000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202201494"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,6,5]]},"references-count":31,"journal-issue":{"issue":"22","published-print":{"date-parts":[[2022,8]]}},"alternative-id":["10.1002\/advs.202201494"],"URL":"https:\/\/doi.org\/10.1002\/advs.202201494","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,6,5]]},"assertion":[{"value":"2022-03-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-06-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2201494"}}