{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T22:59:45Z","timestamp":1777503585523,"version":"3.51.4"},"reference-count":40,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2004,4,16]],"date-time":"2004-04-16T00:00:00Z","timestamp":1082073600000},"content-version":"vor","delay-in-days":1812,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["AIChE Journal"],"published-print":{"date-parts":[[1999,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Adsorption storage is the most promising low\u2010pressure alternative for storing natural gas, but some operational difficulties hinder the success of this technology. From a modeling perspective, this article addresses the impact of gas composition on the cyclic behavior of adsorptive natural gas storage systems. The cyclic operation of an onboard storage reservoir is modeled as a series of consecutive two\u2010step processes, each consisting of charge with a fixed composition gas mixture followed by discharge at constant molar flow rate. Special attention is given to the composition and calorific value of the gas delivered by the storage system and to performance quantifiers that measure net deliverable capacity as a function of cycle number. Evidence of a cyclic steady state is given, and the numerical results are compared with experimental measurements. The results show the need for identifying and evaluating economical means of removing the higher molecular\u2010weight hydrocarbons and other highly adsorbed species from the gas stream before charging the storage reservoir.<\/jats:p>","DOI":"10.1002\/aic.690450509","type":"journal-article","created":{"date-parts":[[2004,4,16]],"date-time":"2004-04-16T14:34:29Z","timestamp":1082126069000},"page":"986-996","source":"Crossref","is-referenced-by-count":51,"title":["Impact of gas composition on natural gas storage by adsorption"],"prefix":"10.1002","volume":"45","author":[{"given":"Jos\u00e9 P. B.","family":"Mota","sequence":"first","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2004,4,16]]},"reference":[{"key":"e_1_2_1_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/0008-6223(88)90111-X"},{"key":"e_1_2_1_3_1","doi-asserted-by":"crossref","unstructured":"BeVier W. E. J. T.Mullhaupt F.Notaro I. C.Lewis andR. E.Coleman \u201cAdsorbent\u2010Enhanced Methane Storage for Alternate Fuel Powered Vehicles \u201d SAE Future Transportation Technology Conf. and Exposition Vancouver B.C. Canada (1989).","DOI":"10.4271\/891638"},{"key":"e_1_2_1_4_1","volume-title":"The Adsorption of Gases and Vapours","author":"Brunauer S.","year":"1945"},{"key":"e_1_2_1_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/1359-4311(95)00017-8"},{"key":"e_1_2_1_6_1","unstructured":"Cook T. L. C.Komodromos D. F.Quinn andS.Ragan \u201cA Low Pressure Natural Gas Vehicle Storage System \u201d Windsor Workshop on Alternative Fuels Toronto Ont. Canada (1996)."},{"key":"e_1_2_1_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-008042683-9\/50011-X"},{"key":"e_1_2_1_8_1","first-page":"266","article-title":"Some Aspects of a Sorbent\u2010Containing Storage System for Natural Gas","volume":"29","author":"Czepirski L.","year":"1991","journal-title":"Indian J. Technol."},{"key":"e_1_2_1_9_1","volume-title":"Progress Surface and Membrane Science","author":"Dubinin M. M.","year":"1975"},{"key":"e_1_2_1_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/0008-6223(89)90078-X"},{"key":"e_1_2_1_11_1","doi-asserted-by":"crossref","unstructured":"Golovoy A. andE. J.Blais \u201cNatural Gas Storage on Activated Carbon \u201dAlternative Fuels for Special Ignition Engines SP\u2010559 SAE Conf. Proc. Warrendale PA p.47(1983).","DOI":"10.4271\/831678"},{"key":"e_1_2_1_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/i160011a009"},{"key":"e_1_2_1_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/i160020a010"},{"key":"e_1_2_1_14_1","volume-title":"Molecular Theory of Gases and Liquids","author":"Hirschfelder J. O.","year":"1954"},{"key":"e_1_2_1_15_1","unstructured":"Jasionowski W. J. A. J.Tiller J. A.Fata J. M.Arnold S. W.Gauthier andY. A.Shikari \u201cCharge\/Discharge Characteristics of High\u2010Capacity Methane Adsorption Storage Systems \u201d Int. Gas Research Conf. Tokyo (1989)."},{"key":"e_1_2_1_16_1","unstructured":"Kasuh T. K.Okawa andT.Maeda \u201cLow Pressure Storage Concept for Natural Gas Fueled Vehicles \u201dProc. Int. Gas Res. Conf. p.485(1992)."},{"key":"e_1_2_1_17_1","doi-asserted-by":"publisher","DOI":"10.1177\/026361749601300610"},{"key":"e_1_2_1_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-6223(97)00115-2"},{"key":"e_1_2_1_19_1","unstructured":"Mota J. P. B. \u201cMod\u00e9lisation des Transferts Coupl\u00e9s en Milieux Poreux \u201d Th\u00e8se de Doctorat Institut National Polytechnique de Lorraine Nancy France (1995)."},{"key":"e_1_2_1_20_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF00704143"},{"key":"e_1_2_1_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01650235"},{"key":"e_1_2_1_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-6223(97)00075-4"},{"key":"e_1_2_1_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0098-1354(96)00280-3"},{"key":"e_1_2_1_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-009-2263-1_2"},{"key":"e_1_2_1_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690110125"},{"key":"e_1_2_1_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9797(76)90149-1"},{"key":"e_1_2_1_27_1","first-page":"291","volume-title":"Porosity in Carbons","author":"Parkyns N. D.","year":"1995"},{"key":"e_1_2_1_28_1","volume-title":"Rep. Ris\u00f8\u2010M\u20102781","author":"Pedersen A. S.","year":"1989"},{"key":"e_1_2_1_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/i260075a002"},{"key":"e_1_2_1_30_1","volume-title":"The Properties of Gases and Liquids","author":"Reid R. C.","year":"1977"},{"key":"e_1_2_1_31_1","volume-title":"Rep. DOE\/NASA\/0327\u20101","author":"Remick R. J.","year":"1984"},{"key":"e_1_2_1_32_1","unstructured":"Remick R. J. andA. J.Tiller \u201cHeat Generation in Natural Gas Adsorption Systems \u201d Gaseous Fuels for Transportation Int. Conf. Vancouver B.C. Canada (1986)."},{"key":"e_1_2_1_33_1","unstructured":"Sangani N. \u201cDesorption Dynamics of Adsorptive Gas Storage Systems \u201d MS Thesis Dept. of Chemical Engineering Cleveland State Univ. Cleveland OH (1990)."},{"key":"e_1_2_1_34_1","unstructured":"Sejnoha M. R.Chahine W.Ya\u00efci andT. K.Bose \u201cAdsorption Storage of Natural Gas on Activated Carbon \u201d AIChE Meeting San Francisco CA (1994)."},{"key":"e_1_2_1_35_1","first-page":"67","volume-title":"Porosity in Carbons","author":"Stoeckli F.","year":"1995"},{"key":"e_1_2_1_36_1","doi-asserted-by":"publisher","DOI":"10.1177\/026361749701500904"},{"key":"e_1_2_1_37_1","unstructured":"Strisna F. W. E.BeVier R.Coleman andS.Gauthier \u201cAdsorbent Storage of Natural Gas \u201dProc. Windsor Workshop on Alternative Fuels p.58(1989)."},{"key":"e_1_2_1_38_1","doi-asserted-by":"crossref","unstructured":"Talu O. \u201cAn Overview of Adsorptive Storage of Natural Gas \u201dProc. Int. Conf. on Fundamentals of Adsorption M. Suzuki ed. Kyoto Japan p.655(1992).","DOI":"10.1016\/S0167-2991(08)63573-9"},{"key":"e_1_2_1_39_1","first-page":"409","volume-title":"Proc. First Separations Division Topical Conf. on Separations Technologies: New Developments and Opportunities","author":"Talu O.","year":"1993"},{"key":"e_1_2_1_40_1","first-page":"95","volume":"46","author":"Wilke C. R.","year":"1950","journal-title":"Chem. Eng. Prog."},{"key":"e_1_2_1_41_1","volume-title":"Gas Separation by Adsorption Processes","author":"Yang R. T.","year":"1987"}],"container-title":["AIChE Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Faic.690450509","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aiche.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/aic.690450509","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,7]],"date-time":"2025-10-07T15:49:17Z","timestamp":1759852157000},"score":1,"resource":{"primary":{"URL":"https:\/\/aiche.onlinelibrary.wiley.com\/doi\/10.1002\/aic.690450509"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1999,5]]},"references-count":40,"journal-issue":{"issue":"5","published-print":{"date-parts":[[1999,5]]}},"alternative-id":["10.1002\/aic.690450509"],"URL":"https:\/\/doi.org\/10.1002\/aic.690450509","archive":["Portico"],"relation":{},"ISSN":["0001-1541","1547-5905"],"issn-type":[{"value":"0001-1541","type":"print"},{"value":"1547-5905","type":"electronic"}],"subject":[],"published":{"date-parts":[[1999,5]]}}}