{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T19:47:58Z","timestamp":1762112878655,"version":"build-2065373602"},"reference-count":68,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2004,4,16]],"date-time":"2004-04-16T00:00:00Z","timestamp":1082073600000},"content-version":"vor","delay-in-days":502,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["AIChE Journal"],"published-print":{"date-parts":[[2002,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A five\u2010step, one\u2010bed, sorption\u2010enhanced reaction process proposed by Carvill et al. in 1996 for hydrogen production by steam\u2013methane reforming was analyzed. For the simulated results of the first step, data from Hufton et al. (1999) and Ding and Alpay (2000) for a fixed\u2010bed column of an admixture of a catalyst and a sorbent that selectively removes CO<jats:sub>2<\/jats:sub> from the reaction zone were used. The sorbent is periodically regenerated by using the principles of pressure\u2010swing adsorption. The process steps allow direct production of hydrogen with high purity and high methane conversion. A model considering multicomponent and overall mass balance, Ergun relation for pressure drop, energy balance for the bed\u2010volume element, and nonlinear adsorption equilibrium isotherm coupled with three main reactions was derived to describe the sorption\u2010enhanced reaction cyclic process. Two different isotherms were used under wet and dry conditions. The LDF model adopted describes the mass\u2010transfer rate of CO<jats:sub>2<\/jats:sub> in the adsorbent. Numerical solution of model equations for the cyclic process was obtained by the orthogonal collocation method. The operating conditions allow the combination of a sufficiently high purity of hydrogen (average purity over 80%) with traces of CO and CO<jats:sub>2<\/jats:sub>, high methane conversion, fast adsorbent regeneration, and cyclic steady\u2010state operation. The model predictions agree reasonably with the literature data. The package is suitable for the design and analysis of sorption\u2010enhanced reaction process.<\/jats:p>","DOI":"10.1002\/aic.690481210","type":"journal-article","created":{"date-parts":[[2004,4,16]],"date-time":"2004-04-16T14:01:16Z","timestamp":1082124076000},"page":"2817-2832","source":"Crossref","is-referenced-by-count":62,"title":["Simulation of five\u2010step one\u2010bed sorption\u2010enhanced reaction process"],"prefix":"10.1002","volume":"48","author":[{"given":"Guo\u2010hua","family":"Xiu","sequence":"first","affiliation":[]},{"given":"Jose Luciano","family":"Soares","sequence":"additional","affiliation":[]},{"given":"Ping","family":"Li","sequence":"additional","affiliation":[]},{"given":"Alirio E.","family":"Rodrigues","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2004,4,16]]},"reference":[{"key":"e_1_2_1_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(94)00324-6"},{"key":"e_1_2_1_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(93)80203-3"},{"key":"e_1_2_1_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(94)00353-X"},{"key":"e_1_2_1_5_1","unstructured":"Anand M. J.Hufton S.Mayorga S.Nataraja S.Sircar andT.Gaffiney \u201cSorption Enhanced Reaction (SERP) for the Production of Hydrogen \u201d APCI Report for DOE DOE Washington DC (1995)."},{"key":"e_1_2_1_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/0920-5861(95)00073-O"},{"key":"e_1_2_1_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(96)00229-5"},{"volume-title":"Transport Phenomena","year":"1960","author":"Bird R. B.","key":"e_1_2_1_8_1"},{"key":"e_1_2_1_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690421008"},{"key":"e_1_2_1_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(90)80124-W"},{"key":"e_1_2_1_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/0920-5861(94)80131-2"},{"key":"e_1_2_1_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(80)80072-8"},{"key":"e_1_2_1_13_1","doi-asserted-by":"publisher","DOI":"10.1098\/rspa.1982.0125"},{"key":"e_1_2_1_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/i260037a009"},{"key":"e_1_2_1_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690470212"},{"key":"e_1_2_1_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(72)87012-X"},{"key":"e_1_2_1_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(99)00596-5"},{"key":"e_1_2_1_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(99)00597-7"},{"key":"e_1_2_1_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(68)87056-3"},{"key":"e_1_2_1_20_1","first-page":"89","article-title":"Fluid Flow Through Packed Columns","volume":"48","author":"Ergun S.","year":"1952","journal-title":"Chem. Eng. Prog."},{"key":"e_1_2_1_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(86)87143-3"},{"key":"e_1_2_1_22_1","unstructured":"Gluud W. K.Keller R.Schonfelder andW.Klempt \u201cProduction of Hydrogen \u201d U. S. Patent No. 1 816 523 (1931)."},{"key":"e_1_2_1_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(94)00266-5"},{"key":"e_1_2_1_24_1","doi-asserted-by":"publisher","DOI":"10.1080\/00986448008935944"},{"key":"e_1_2_1_25_1","first-page":"53","article-title":"Inorganic Membrane Reactors\u2014A Review","volume":"85","author":"Hsieh H. P.","year":"1989","journal-title":"AIChE Symp. Ser."},{"key":"e_1_2_1_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690450205"},{"key":"e_1_2_1_27_1","first-page":"70","article-title":"Sorption Enhanced Reaction Process (SERP) for the Production of Hydrogen","volume":"1","author":"Hufton J. R.","year":"2000","journal-title":"Proc. U.S. DOE Hydrogen Program Rev."},{"key":"e_1_2_1_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie00023a026"},{"key":"e_1_2_1_29_1","first-page":"255","article-title":"Process Intensification: Polymer Film Compact Heat Exchanger (PFCHE)","volume":"72","author":"Jachuck R. J. J.","year":"1994","journal-title":"Chem. Eng. Res. Des."},{"key":"e_1_2_1_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie00023a038"},{"key":"e_1_2_1_31_1","first-page":"541","article-title":"A Theoretical Investigation of Pressure Swing Reaction","volume":"72","author":"Kirkby N. F.","year":"1994","journal-title":"Trans. Inst. Chem. Eng."},{"key":"e_1_2_1_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(05)80053-3"},{"key":"e_1_2_1_33_1","first-page":"167","article-title":"Effects of Adsorbent and Catalyst Distributions in Pressure Swing Reactors","volume":"84","author":"Lee I. D.","year":"1989","journal-title":"AIChE Symp. Ser."},{"key":"e_1_2_1_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(77)80143-7"},{"key":"e_1_2_1_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690400705"},{"key":"e_1_2_1_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690180610"},{"key":"e_1_2_1_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690190531"},{"key":"e_1_2_1_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/i160005a007"},{"key":"e_1_2_1_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690431013"},{"key":"e_1_2_1_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie00044a016"},{"key":"e_1_2_1_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0376-7388(98)00291-9"},{"key":"e_1_2_1_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjce.5450770223"},{"key":"e_1_2_1_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(85)85125-3"},{"volume-title":"The Properties of Gases and Liquids","year":"1988","author":"Reid R. C.","key":"e_1_2_1_44_1"},{"key":"e_1_2_1_45_1","first-page":"225","volume-title":"Catalyst Handbook","author":"Ridler D. E.","year":"1989"},{"key":"e_1_2_1_46_1","first-page":"529","article-title":"Catalytic Reactions and Catalysis under Chromatographic Reactor","volume":"3","author":"Roginskii S. Z.","year":"1962","journal-title":"Kinet. Katal."},{"key":"e_1_2_1_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/0920-5861(93)85027-W"},{"key":"e_1_2_1_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(96)00328-4"},{"key":"e_1_2_1_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/0950-4214(93)80006-I"},{"key":"e_1_2_1_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1383-5866(98)00043-4"},{"key":"e_1_2_1_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie00079a008"},{"key":"e_1_2_1_52_1","doi-asserted-by":"publisher","DOI":"10.1252\/jcej.10.455"},{"key":"e_1_2_1_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(05)80048-X"},{"key":"e_1_2_1_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(05)80049-1"},{"key":"e_1_2_1_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(92)87149-K"},{"volume-title":"Catalyst Handbook","year":"1989","author":"Twigg M. V.","key":"e_1_2_1_56_1"},{"key":"e_1_2_1_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie00051a022"},{"key":"e_1_2_1_58_1","first-page":"39","volume-title":"Adsorption Equilibrium Data Handbook","author":"Valenzuela D. P.","year":"1989"},{"key":"e_1_2_1_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690330810"},{"key":"e_1_2_1_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690350514"},{"key":"e_1_2_1_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690470623"},{"key":"e_1_2_1_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/je00031a005"},{"key":"e_1_2_1_63_1","doi-asserted-by":"publisher","DOI":"10.1080\/01496399008050405"},{"key":"e_1_2_1_64_1","doi-asserted-by":"crossref","unstructured":"Xiu G. H. P.Li andA. E.Rodrigues \u201cSorption\u2010Enhanced Reaction Process with Intraparticle Diffusion Limitation \u201dProc. Int. Symp. on Chemical Reaction Engineering Hong Kong (2002).","DOI":"10.1016\/S0009-2509(02)00245-2"},{"key":"e_1_2_1_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690350109"},{"key":"e_1_2_1_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690060407"},{"key":"e_1_2_1_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(97)00369-2"},{"key":"e_1_2_1_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(98)00467-9"},{"key":"e_1_2_1_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie000238w"}],"container-title":["AIChE Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Faic.690481210","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aiche.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/aic.690481210","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,7]],"date-time":"2025-10-07T22:45:11Z","timestamp":1759877111000},"score":1,"resource":{"primary":{"URL":"https:\/\/aiche.onlinelibrary.wiley.com\/doi\/10.1002\/aic.690481210"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2002,12]]},"references-count":68,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2002,12]]}},"alternative-id":["10.1002\/aic.690481210"],"URL":"https:\/\/doi.org\/10.1002\/aic.690481210","archive":["Portico"],"relation":{},"ISSN":["0001-1541","1547-5905"],"issn-type":[{"type":"print","value":"0001-1541"},{"type":"electronic","value":"1547-5905"}],"subject":[],"published":{"date-parts":[[2002,12]]}}}