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The reaction requires low catalyst loading, shows high selectivity for the formation of the imine without the need of adding any base or additive, and can be scaled up. Interestingly, when the catalytic reaction is performed in a closed system, in the presence of base, the reaction selectively yields the corresponding amine. To highlight the practical utility of the synthesis of imines, a family of structurally important scaffold, an indole, were synthesized.<\/jats:p>","DOI":"10.1002\/ajoc.202300282","type":"journal-article","created":{"date-parts":[[2023,7,11]],"date-time":"2023-07-11T11:10:12Z","timestamp":1689073812000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Pd\u2010Catalyzed Switchable Access to Imines and Amines from Secondary Alcohols"],"prefix":"10.1002","volume":"12","author":[{"given":"Daniel","family":"Raydan","sequence":"first","affiliation":[{"name":"LAQV-REQUIMTE Departamento de Qu\u00edmica Faculdade de Ci\u00eancias e Tecnologia Universidade Nova de Lisboa  Campus de Caparica 2829-516 Caparica Portugal"},{"name":"ITQB NOVA Instituto de Tecnologia Qu\u00edmica e Biol\u00f3gica Ant\u00f3nio Xavier Universidade Nova de Lisboa  Av. da Rep\u00fablica 2780-157 Oeiras Portugal"}]},{"given":"Beatriz","family":"Royo","sequence":"additional","affiliation":[{"name":"ITQB NOVA Instituto de Tecnologia Qu\u00edmica e Biol\u00f3gica Ant\u00f3nio Xavier Universidade Nova de Lisboa  Av. da Rep\u00fablica 2780-157 Oeiras Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6712-752X","authenticated-orcid":false,"given":"M. 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