{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T04:56:59Z","timestamp":1790830619313,"version":"4.1.0"},"reference-count":45,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100000937","name":"M.J. Murdock Charitable Trust","doi-asserted-by":"publisher","award":["SR\u20102017297"],"award-info":[{"award-number":["SR\u20102017297"]}],"id":[{"id":"10.13039\/100000937","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE\u2010AC02\u201006CH11357"],"award-info":[{"award-number":["DE\u2010AC02\u201006CH11357"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angewandte Chemie"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Achieving sustainable carbon capture under realistic, humid conditions remains a central challenge for decarbonization technologies. Here we report an ultramicroporous oxofluorovanadate metal\u2010organic framework, Ni(pyrazine)\n                    <jats:sub>2<\/jats:sub>\n                    (VOF\n                    <jats:sub>4<\/jats:sub>\n                    ), that dynamically regulates competitive adsorption through reversible redox chemistry. Under humid dilute CO\n                    <jats:sub>2<\/jats:sub>\n                    streams (4 vol%), water chemisorbs at vanadium centers in the form of hydroxide ligands and induces a reversible V(+4)|V(+5) transformation to an isoreticular phase, Ni(pyrazine)\n                    <jats:sub>2<\/jats:sub>\n                    (VO(OH)F\n                    <jats:sub>4<\/jats:sub>\n                    ), while CO\n                    <jats:sub>2<\/jats:sub>\n                    is engaged in strong physisorption within pyrazine\u2010lined pore regions. This redox\u2010driven compartmentalization of H\n                    <jats:sub>2<\/jats:sub>\n                    O and CO\n                    <jats:sub>2<\/jats:sub>\n                    results in a dynamic breakthrough CO\n                    <jats:sub>2<\/jats:sub>\n                    capacity of 2.04 \u00b1 0.07\u00a0mmol\/g, sustained for up to 50 cycles and showing resilience under intense humidification or steam exposure. These findings establish redox\u2010adaptive adsorption in BVR\u2010X as a unique design paradigm, enabling scalable and durable carbon capture under realistic operating conditions.\n                  <\/jats:p>","DOI":"10.1002\/ange.9809119","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T04:17:02Z","timestamp":1790828222000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Pore Compartmentalization of CO\n                    <sub>2<\/sub>\n                    and H\n                    <sub>2<\/sub>\n                    O in a Redox\u2010Active Adsorbent"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4326-6776","authenticated-orcid":false,"given":"Ankit K.","family":"Yadav","sequence":"first","affiliation":[{"name":"Materials Discovery Laboratory Department of Chemistry Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-7434-3732","authenticated-orcid":false,"given":"Emmanuel N.","family":"Musa","sequence":"additional","affiliation":[{"name":"Materials Discovery Laboratory Department of Chemistry Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7931-0148","authenticated-orcid":false,"given":"Ah\u2010Young","family":"Song","sequence":"additional","affiliation":[{"name":"College of Chemistry Pines Magnetic Resonance Center University of California  Berkeley California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7606-6864","authenticated-orcid":false,"given":"Alireza","family":"Pourghaderi","sequence":"additional","affiliation":[{"name":"College of Chemistry Pines Magnetic Resonance Center University of California  Berkeley California USA"},{"name":"Department of Chemical and Biomolecular Engineering University of California  Berkeley California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-6633-0191","authenticated-orcid":false,"given":"Micah","family":"Lee Wilson","sequence":"additional","affiliation":[{"name":"School of Chemical Biological and Environmental Engineering Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8285-9227","authenticated-orcid":false,"given":"Chun\u2010Wai","family":"Chang","sequence":"additional","affiliation":[{"name":"School of Chemical Biological and Environmental Engineering Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-3779-2712","authenticated-orcid":false,"given":"Kai Shen","family":"Choong","sequence":"additional","affiliation":[{"name":"School of Chemical Biological and Environmental Engineering Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8024-6996","authenticated-orcid":false,"given":"Casey R.","family":"Simons","sequence":"additional","affiliation":[{"name":"Center For Advanced Materials Characterization in Oregon University of Oregon  Eugene Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7598-5076","authenticated-orcid":false,"given":"Zhenxing","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Chemical Biological and Environmental Engineering Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4191-3725","authenticated-orcid":false,"given":"Jeffrey A.","family":"Reimer","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of California  Berkeley California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ammar","family":"Alahmed","sequence":"additional","affiliation":[{"name":"ARAMCO Research and Development Center  Dhahran Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2296-6530","authenticated-orcid":false,"given":"Mourad","family":"Younes","sequence":"additional","affiliation":[{"name":"ARAMCO Research and Development Center  Dhahran Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6577-0538","authenticated-orcid":false,"given":"Aqil","family":"Jamal","sequence":"additional","affiliation":[{"name":"ARAMCO Research and Development Center  Dhahran Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3302-1644","authenticated-orcid":false,"given":"Andrzej","family":"G\u0142adysiak","sequence":"additional","affiliation":[{"name":"Materials Discovery Laboratory Department of Chemistry Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1670-0020","authenticated-orcid":false,"given":"Kyriakos C.","family":"Stylianou","sequence":"additional","affiliation":[{"name":"Materials Discovery Laboratory Department of Chemistry Oregon State University  Corvallis Oregon USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,30]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1175\/1520\u20100469(1967)024<0241:TEOTAW>2.0.CO;2"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010023\u201001132\u20106"},{"key":"e_1_2_10_4_1","unstructured":"E.DelarueandJ.Morris \u201cRenewables Intermittency: Operational Limits and Implications for Long\u2010Term Energy System Models. Joint Program Report Series Report 277 \u201d MIT Joint Program on the Science and Policy of Global Change (2015)."},{"key":"e_1_2_10_5_1","unstructured":"U.S. Department of Energy Office of Energy Statistics U.S. Energy Information Administration. Short\u2010Term Energy Outlook(accessed 2025\u201005\u201022)May 2025 https:\/\/www.eia.gov\/outlooks\/steo\/."},{"key":"e_1_2_10_6_1","unstructured":"N.Kuehn E.Lewis M.Woods et\u00a0al. \u201cCost and Performance Baseline for Fossil Energy Plants \u201d Volume 1: Bituminous Coal and Natural Gas to Electricity Revision 2 November 2010. DOE\/NETL\u20102010\/1397 (National Energy Technology Laboratory 2010)."},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1142\/p911"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527821099"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr2003272"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202010047"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b00838"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11893"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.1500421"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c12200"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abi7281"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202206613"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.4c00923"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aab1680"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010019\u20101798\u20107"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470994429"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00442A"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50046a012"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb\u20101976\u20100502"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c00947"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.2c02049"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201007427\u2010z"},{"key":"e_1_2_10_27_1","volume-title":"Infrared and Raman Spectra of Inorganic and Coordination Compounds","author":"Nakamoto K.","year":"2008"},{"key":"e_1_2_10_28_1","volume-title":"The Organometallic Chemistry of the Transition Metals","author":"Crabtree R. H.","year":"2001"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2012.01.033"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c01305"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05345"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC02289A"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5228"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC03196H"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5c02564"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11503"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c09173"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202418272"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04910"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202503369"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202502988"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aam8310"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05567"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2023.101470"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010024\u201008080\u2010x"},{"key":"e_1_2_10_46_1","unstructured":"Deposition Numbers CCDC 2536722 and 2536723 contain the supplementary crystallographic data for all the compounds reported in this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe (http:\/\/www.ccdc.cam.ac.uk\/structures)."}],"container-title":["Angewandte Chemie"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ange.9809119","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/ange.9809119","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ange.9809119","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T04:17:06Z","timestamp":1790828226000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/ange.9809119"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,30]]},"references-count":45,"alternative-id":["10.1002\/ange.9809119"],"URL":"https:\/\/doi.org\/10.1002\/ange.9809119","archive":["Portico"],"relation":{},"ISSN":["0044-8249","1521-3757"],"issn-type":[{"value":"0044-8249","type":"print"},{"value":"1521-3757","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,30]]},"assertion":[{"value":"2026-08-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-04","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e9809119"}}