{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,21]],"date-time":"2025-09-21T17:31:53Z","timestamp":1758475913736},"reference-count":6,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2003,12,22]],"date-time":"2003-12-22T00:00:00Z","timestamp":1072051200000},"content-version":"vor","delay-in-days":6413,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew. Chem. Int. Ed. Engl."],"published-print":{"date-parts":[[1986,6]]},"abstract":"<jats:p><jats:bold>A dramatic high\u2010field shift of an <jats:sup>1<\/jats:sup>H\u2010NMR signal<\/jats:bold> characterizes the agostic Mo\u21bcH\uf8ffC interaction in the isopropylmolybdenum complex <jats:bold>2<\/jats:bold>. The bright yellow compound is accessible in 65% yield by reaction of the binuclear molybdenum complex <jats:bold>1<\/jats:bold> with isopropylmagnesium chloride at \u221278\u00b0C in ether. <jats:disp-formula>\n<jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" position=\"anchor\" xlink:href=\"urn:x-wiley:05700833:media:ANIE198605551:nueqn001\"><jats:alt-text>equation image<\/jats:alt-text><\/jats:graphic>\n<\/jats:disp-formula><\/jats:p>","DOI":"10.1002\/anie.198605551","type":"journal-article","created":{"date-parts":[[2003,12,31]],"date-time":"2003-12-31T09:18:20Z","timestamp":1072862300000},"page":"555-556","source":"Crossref","is-referenced-by-count":9,"title":["[MoR(\u03b7<sup>3<\/sup>\u2010C<sub>3<\/sub>H<sub>5<\/sub>)<sub>3<\/sub>], R = Alkyl: Alkylmolybdenum Complexes with Agostic C\uf8ffH \u21c0 Mo Bond"],"prefix":"10.1002","volume":"25","author":[{"given":"Reinhard","family":"Benn","sequence":"first","affiliation":[]},{"given":"Sigrid","family":"Holle","sequence":"additional","affiliation":[]},{"given":"Peter W.","family":"Jolly","sequence":"additional","affiliation":[]},{"given":"Richard","family":"Mynott","sequence":"additional","affiliation":[]},{"given":"Carlos C.","family":"Rom\u00e3o","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2003,12,22]]},"reference":[{"key":"e_1_2_1_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00084a021"},{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)84950-5"},{"key":"e_1_2_1_3_2","unstructured":"The termagostichas been introduced [4] to describe the various degrees of interaction between a carbon\u2010bonded H atom and a transition\u2010metal atom (C\u2010H \u21c4 M)."},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(83)85065-7"},{"key":"e_1_2_1_4_3","doi-asserted-by":"publisher","DOI":"10.1021\/ja00291a073"},{"key":"e_1_2_1_5_2","unstructured":"4 R = Me:1H\u2010NMR (400 MHz [D8]THF \u221280 \u00b0C): \u03b4 = 4.37 (m meso\u2010H) 1.89 (br. s syn\u2010H) 1.23 (m \uf8feCH2) 1.10 (t Me) 0.94 (m anti\u2010H) 0.76 (m anti\u2010H) 0.54 (d \uf8feCH2) 0.38 (m syn\u2010H).31P\u2010NMR (32.4 MHz [D6]acetone \u221230\u00b0C): \u03b4 = 12.1."}],"container-title":["Angewandte Chemie International Edition in English"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.198605551","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.198605551","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,20]],"date-time":"2023-10-20T20:40:15Z","timestamp":1697834415000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.198605551"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1986,6]]},"references-count":6,"journal-issue":{"issue":"6","published-print":{"date-parts":[[1986,6]]}},"alternative-id":["10.1002\/anie.198605551"],"URL":"https:\/\/doi.org\/10.1002\/anie.198605551","archive":["Portico"],"relation":{},"ISSN":["0570-0833"],"issn-type":[{"value":"0570-0833","type":"print"}],"subject":[],"published":{"date-parts":[[1986,6]]}}}