{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,15]],"date-time":"2026-04-15T14:32:22Z","timestamp":1776263542783,"version":"3.50.1"},"reference-count":25,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2003,12,22]],"date-time":"2003-12-22T00:00:00Z","timestamp":1072051200000},"content-version":"vor","delay-in-days":2229,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew. Chem. Int. Ed. Engl."],"published-print":{"date-parts":[[1997,11,14]]},"DOI":"10.1002\/anie.199723241","type":"journal-article","created":{"date-parts":[[2003,12,31]],"date-time":"2003-12-31T09:22:19Z","timestamp":1072862539000},"page":"2324-2326","source":"Crossref","is-referenced-by-count":50,"title":["An Organic Spin\u2010Ladder Molecular Material"],"prefix":"10.1002","volume":"36","author":[{"given":"Concepci\u00f3","family":"Rovira","sequence":"first","affiliation":[]},{"given":"Jaume","family":"Veciana","sequence":"additional","affiliation":[]},{"given":"Elisabet","family":"Ribera","sequence":"additional","affiliation":[]},{"given":"Judit","family":"Tarr\u00e9s","sequence":"additional","affiliation":[]},{"given":"Enric","family":"Canadell","sequence":"additional","affiliation":[]},{"given":"Roger","family":"Rousseau","sequence":"additional","affiliation":[]},{"given":"Montserrat","family":"Mas","sequence":"additional","affiliation":[]},{"given":"Elies","family":"Molins","sequence":"additional","affiliation":[]},{"given":"Manuel","family":"Almeida","sequence":"additional","affiliation":[]},{"given":"Rui T.","family":"Henriques","sequence":"additional","affiliation":[]},{"given":"Jorge","family":"Morgado","sequence":"additional","affiliation":[]},{"given":"Jean\u2010Philippe","family":"Schoeffel","sequence":"additional","affiliation":[]},{"given":"Jean\u2010Paul","family":"Pouget","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2003,12,22]]},"reference":[{"key":"e_1_2_1_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.271.5249.618"},{"key":"e_1_2_1_1_3","doi-asserted-by":"publisher","DOI":"10.1038\/377041a0"},{"key":"e_1_2_1_1_4","doi-asserted-by":"publisher","DOI":"10.1038\/377012a0"},{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.45.5744"},{"key":"e_1_2_1_2_3","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.49.8901"},{"key":"e_1_2_1_2_4","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.6817"},{"key":"e_1_2_1_2_5","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.73.882"},{"key":"e_1_2_1_2_6","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.75.926"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.R6838"},{"key":"e_1_2_1_3_3","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.73.2626"},{"key":"e_1_2_1_3_4","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.73.3463"},{"key":"e_1_2_1_3_5","doi-asserted-by":"publisher","DOI":"10.1209\/0295-5075\/23\/6\/011"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-011-2612-0_12"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00091a017"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.19950070230"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50010a031"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.19.730"},{"key":"e_1_2_1_9_2","unstructured":"Crystallographic data for C28H16N4S16Au: crystal dimensions 0.37 \u00d7 0.23 \u00d7 0.065 mm;Mr= 1110.31 monoclinic space groupP21\/n a= 16.334(1) b= 3.912(1) c= 27.348(2) \u00c5 \u03b2 = 101.787(6)\u00b0Z= 2;V= 1710.7(2) \u00c53 \u03c1calcd= 2.16 g cm\u22123. Data were collected at 293 K on an Enraf\u2010Nonius CAD4 diffractometer equipped with a Mo X\u2010ray tube and a graphite monochromator selected MoK\u03b1radiation (absorption coefficient \u03bc = 5.31 mm\u22121). Data collection up to 2\u03b8 = 62\u00b0 and \u221223 \u2264h\u2264 23 0 \u2264k\u2264 5 \u221239 \u2264 l \u2264 0 affords 7898 reflections measured with \u03c9\u20132\u03b8 scans. Lorentz polarization and absorption (DIFABS: max\/min absoption factors 1.254\/0.793) effects were corrected. The structure was refined using full\u2010matrix least\u2010squares methods (SHELXL\u201093). The minimized function was \u03c9(F\u2013F)2with \u03c9 = 1\/\u03c32F2+(AP)2+BPandA= 0.0419 B= 0.57 P= [Max(0.Fo) +2Fc]\/3 ands the standard deviation estimated from counting statistics. At convergence the finalRindices wereR1= 0.068 wR2= 0.078 (for all data) andR1= 0.027 wR2= 0.066 (forI> 2\u03c3(I) reflections). The final max\/min residuals were 1.11\/\u20130.91 e\u00c5\u22123. Crystalographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC\u2010100 375. Copies of the data can be obtained free of charge on application to The Director CCDC 12 Union Road Cambridge CB21EZ UK (fax: int. code +(1223) 336\u2010033; e\u2010mail: deposit@chemcrys.cam.ac.uk)."},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00097a016"},{"key":"e_1_2_1_10_3","doi-asserted-by":"publisher","DOI":"10.1063\/1.1734456"},{"key":"e_1_2_1_10_4","doi-asserted-by":"publisher","DOI":"10.1021\/ja00480a005"},{"key":"e_1_2_1_11_2","unstructured":"The experiment was performed with the so\u2010called \u201cfixed film\u2010fixed crystal\u201d method with a monochromatized CuK\u03b1(\u03bb = 1.542 \u00c5) beam."},{"key":"e_1_2_1_12_2","unstructured":"The ESR spectra consists in a single Loerntzian line in all the orientations of the crystal with respect to the external magnetic field. The room temperature line\u2010widths measured in the three orthogonal orientations of the crystal are \u0394Hpp= 42 25 and 26 G withgfactors of 2.0127 2.0050 and 2.0020 respectively."},{"key":"e_1_2_1_13_2","unstructured":"Magnetic susceptibility was measured by the Faraday method in the range 4\u2013300 K in a polycrystalline sample with an applied magnetic field of 1 T. A from tabulated Pascal constants was applied."},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.13515"}],"container-title":["Angewandte Chemie International Edition in English"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.199723241","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.199723241","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,27]],"date-time":"2023-10-27T21:36:10Z","timestamp":1698442570000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.199723241"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1997,11,14]]},"references-count":25,"journal-issue":{"issue":"21","published-print":{"date-parts":[[1997,11,14]]}},"alternative-id":["10.1002\/anie.199723241"],"URL":"https:\/\/doi.org\/10.1002\/anie.199723241","archive":["Portico"],"relation":{},"ISSN":["0570-0833"],"issn-type":[{"value":"0570-0833","type":"print"}],"subject":[],"published":{"date-parts":[[1997,11,14]]}}}