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Direct solar charging of an auspicious type of redox flow battery could make solar energy directly and efficiently dispatchable. The first solar aqueous alkaline redox flow battery using low cost and environmentally safe materials is demonstrated. The electrolytes consist of the redox couples ferrocyanide and anthraquinone\u20102,7\u2010disulphonate in sodium hydroxide solution, yielding a standard cell potential of 0.74\u2005V. 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