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Ab initio calculations reveal that the primary assumption of Bleaney's theory\u2014that thermal energy is larger than the ligand field splitting\u2014does not hold for the lanthanide complexes in question, and likely for a large fraction of lanthanide complexes in general. This makes the orientation of the magnetic susceptibility tensor differ significantly between complexes of different lanthanides with the same ligand: one of the most popular assumptions about isostructural lanthanide series is wrong.<\/jats:p>","DOI":"10.1002\/anie.201706931","type":"journal-article","created":{"date-parts":[[2017,8,1]],"date-time":"2017-08-01T14:24:01Z","timestamp":1501597441000},"page":"12215-12218","source":"Crossref","is-referenced-by-count":47,"title":["Beyond Bleaney's Theory: Experimental and Theoretical Analysis of Periodic Trends in Lanthanide\u2010Induced Chemical Shift"],"prefix":"10.1002","volume":"56","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4407-1882","authenticated-orcid":false,"given":"Elizaveta A.","family":"Suturina","sequence":"first","affiliation":[{"name":"School of Chemistry University of Southampton  Highfield Campus Southampton SO17 1BJ UK"}]},{"given":"Kevin","family":"Mason","sequence":"additional","affiliation":[{"name":"Department of Chemistry Durham University  South Road Durham DH1 3LE UK"}]},{"given":"Carlos F. 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