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Here, oligomers of <jats:italic>meta<\/jats:italic>\u2010polyaniline, a known ferromagnetic polymer, were synthesized from <jats:italic>para<\/jats:italic>\u2010aminophenol building\u2010blocks via an unexpected and highly specific on\u2010surface formal 1,4 Michael\u2010type addition at the <jats:italic>meta<\/jats:italic> position, driven by the reduction of the aminophenol molecule. We rationalize this dehydrogenation and coupling reaction mechanism with a combination of in situ scanning tunneling and non\u2010contact atomic force microscopies, high\u2010resolution synchrotron\u2010based X\u2010ray photoemission spectroscopy and first\u2010principles calculations. This study demonstrates the capability of surfaces to selectively modify local molecular conditions to redirect well\u2010established synthetic routes, such as Michael coupling, towards the rational synthesis of new covalent nanostructures.<\/jats:p>","DOI":"10.1002\/anie.202009863","type":"journal-article","created":{"date-parts":[[2020,8,6]],"date-time":"2020-08-06T03:33:00Z","timestamp":1596684780000},"page":"23220-23227","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["On\u2010Surface Driven Formal Michael Addition Produces <i>m<\/i>\u2010Polyaniline Oligomers on Pt(111)"],"prefix":"10.1002","volume":"59","author":[{"given":"Nerea","family":"Ruiz del \u00c1rbol","sequence":"first","affiliation":[{"name":"ESISNA Group, Materials Science Factory Institute of Materials Science of Madrid (ICMM-CSIC)  Sor Juana In\u00e9s de la Cruz 3 28049 Madrid Spain"}]},{"given":"Carlos","family":"S\u00e1nchez\u2010S\u00e1nchez","sequence":"additional","affiliation":[{"name":"ESISNA Group, Materials Science Factory Institute of Materials Science of Madrid (ICMM-CSIC)  Sor Juana In\u00e9s de la Cruz 3 28049 Madrid Spain"}]},{"given":"Gonzalo","family":"Otero\u2010Irurueta","sequence":"additional","affiliation":[{"name":"Centre for Mechanical Technology and Automation (TEMA) University of Aveiro  3810-193 Aveiro Portugal"}]},{"given":"Jos\u00e9 I.","family":"Mart\u00ednez","sequence":"additional","affiliation":[{"name":"ESISNA Group, Materials Science Factory Institute of Materials Science of Madrid (ICMM-CSIC)  Sor Juana In\u00e9s de la Cruz 3 28049 Madrid Spain"}]},{"given":"Pedro L.","family":"de Andr\u00e9s","sequence":"additional","affiliation":[{"name":"ESISNA Group, Materials Science Factory Institute of Materials Science of Madrid (ICMM-CSIC)  Sor Juana In\u00e9s de la Cruz 3 28049 Madrid Spain"}]},{"given":"Ana C.","family":"G\u00f3mez\u2010Herrero","sequence":"additional","affiliation":[{"name":"ESISNA Group, Materials Science Factory Institute of Materials Science of Madrid (ICMM-CSIC)  Sor Juana In\u00e9s de la Cruz 3 28049 Madrid Spain"}]},{"given":"Pablo","family":"Merino","sequence":"additional","affiliation":[{"name":"ESISNA Group, Materials Science Factory Institute of Materials Science of Madrid (ICMM-CSIC)  Sor Juana In\u00e9s de la Cruz 3 28049 Madrid Spain"}]},{"given":"Marten","family":"Piantek","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia de Materiales de Arag\u00f3n CSIC-Universidad de Zaragoza  50009 Zaragoza Spain"}]},{"given":"David","family":"Serrate","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia de Materiales de Arag\u00f3n CSIC-Universidad de Zaragoza  50009 Zaragoza Spain"}]},{"given":"Paolo","family":"Lacovig","sequence":"additional","affiliation":[{"name":"Elettra\u2014Sincrotrone Trieste S.C.p.A.  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