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However, under ambient conditions, their selective adsorption is generally impaired due to a high OMS affinity to water. This led previously to the privilege selection of hydrophobic MOFs for the selective capture\/detection of volatile organic compounds (VOCs). Herein, we show that this paradigm is challenged by metal(III) polycarboxylates MOFs, bearing a high concentration of OMS, as MIL\u2010100(Fe), enabling the selective capture of polar VOCs even in the presence of water. With experimental and computational tools, including single\u2010component gravimetric and dynamic mixture adsorption measurements, in situ infrared (IR) spectroscopy and Density Functional Theory calculations we reveal that this adsorption mechanism involves a direct coordination of the VOC on the OMS, associated with an interaction energy that exceeds that of water. Hence, MOFs with OMS are demonstrated to be of interest for air purification purposes.<\/jats:p>","DOI":"10.1002\/anie.202211583","type":"journal-article","created":{"date-parts":[[2022,12,5]],"date-time":"2022-12-05T09:25:42Z","timestamp":1670232342000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":72,"title":["MOFs with Open Metal(III) Sites for the Environmental Capture of Polar Volatile Organic Compounds"],"prefix":"10.1002","volume":"62","author":[{"given":"Maria In\u00eas","family":"Severino","sequence":"first","affiliation":[{"name":"Institut des Mat\u00e9riaux Poreux de Paris (IMAP) ESPCI Paris Ecole Normale Sup\u00e9rieure CNRS PSL University  75005 Paris France"}]},{"given":"Abeer","family":"Al Mohtar","sequence":"additional","affiliation":[{"name":"CERENA Departamento de Engenharia Qu\u00edmica Instituto Superior T\u00e9cnico Universidade de Lisboa  1049-001 Lisboa Portugal"}]},{"given":"Carla","family":"Vieira Soares","sequence":"additional","affiliation":[{"name":"ICGM Univ. 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