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In a ball mill, mixing copper\u2005(I) bromide with zinc\u2005(II), nickel\u2005(II) or copper\u2005(II) acetates, in the presence of (PTA\u2010CH<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>\u2010<jats:italic>p<\/jats:italic>\u2010COOH) Br (PTA is 1,3,5\u2010triaza\u20107\u2010phosphaadamantane) as an organic linker, has produced the corresponding HMOPFs based on Cu<jats:sup>+<\/jats:sup>\u2010Zn<jats:sup>2+<\/jats:sup>, Cu<jats:sup>+<\/jats:sup>\u2010Ni<jats:sup>2+<\/jats:sup> and Cu<jats:sup>+<\/jats:sup>\u2010Cu<jats:sup>2+<\/jats:sup>, respectively. The pyrolysis of HMOPFs resulted in bimetallic nanoparticles of transition metal phosphide and phosphate embedded in multi\u2010P,N,Br\u2010codoped carbon matrices (Cu\u2212M@C). Due to the utilization of an aminophosphine organic linker, this HMOPFs\u2010derived approach typifies an eco\u2010friendly synthesis of carbon confined transition metal phosphides or phosphates. It avoids the common conventional methods that involves phosphorylation using large amounts of additional P sources, which leads to an intensive release of the flammable and poisonous phosphine gas. Also, the presence of Br at the organic linker eliminates the need for using bromine vapours to obtain halogen\u2010doped carbon matrices. The Cu\u2212M@C nanocomposites were tested as negative electrode materials for asymmetric supercapacitors. Electrochemical tests included cyclic voltammetry and galvanostatic charge\u2010discharge experiments, which revealed the Cu\u2212Zn@C electrode with a higher potential window as compared to Cu\u2212Ni@C and Cu\u2212Cu@C electrodes, achieving a rate performance of 60\u2009% and high coulombic efficiency.<\/jats:p>","DOI":"10.1002\/batt.202300564","type":"journal-article","created":{"date-parts":[[2023,12,13]],"date-time":"2023-12-13T08:17:16Z","timestamp":1702455436000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Bimetallic Nanoparticles Embedded in P,N,Br\u2010Codoped Carbon Matrices Derived from Heterometallic\u2010Organophosphine Frameworks as Electrode Materials for Asymmetric Supercapacitors"],"prefix":"10.1002","volume":"7","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8212-2102","authenticated-orcid":false,"given":"Abdallah G.","family":"Mahmoud","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Institute of Molecular Sciences Instituto Superior T\u00e9cnico Universidade de Lisboa  Lisbon Av. Rovisco Pais 1049-001 Lisboa Portugal."},{"name":"Department of Chemistry Faculty of Science Helwan University  Ain Helwan Cairo 11795 Egypt."}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4240-3863","authenticated-orcid":false,"given":"J\u00e9ssica V.","family":"Nardeli","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Institute of Molecular Sciences DEQ Instituto Superior T\u00e9cnico Universidade de Lisboa  Av Rovisco Pais 1049-001 Lisboa Portugal."}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7909-637X","authenticated-orcid":false,"given":"Maria Jo\u00e3o","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Institute of Molecular Sciences Instituto Superior T\u00e9cnico Universidade de Lisboa  Lisbon Av. 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