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However, the\n                    <jats:sup>1<\/jats:sup>\n                    H resolution and sensitivity in ssNMR are often limited for detailed studies, especially for rigid and highly heterogeneous samples, such as intact fungal cells. Here, we conducted a detailed study on\n                    <jats:sup>1<\/jats:sup>\n                    H line width and\n                    <jats:sup>1<\/jats:sup>\n                    H\n                    <jats:italic>T<\/jats:italic>\n                    \u2032\n                    <jats:sub>2<\/jats:sub>\n                    coherence times in the rigid core of the human pathogenic\n                    <jats:italic>Candida albicans<\/jats:italic>\n                    fungal glycans at 60\u2013150\u2009kHz MAS rates and partial fungal cell wall deuteration schemes. We showcased the possibilities and limitations of\n                    <jats:sup>1<\/jats:sup>\n                    H\u2010detected multidimensional\n                    <jats:sup>1<\/jats:sup>\n                    H\/\n                    <jats:sup>13<\/jats:sup>\n                    C chemical shift assignment experiments for rigid cell wall glycans. Furthermore, we probed dynamics using relaxation measurements, providing access to motions spanning from nanoseconds to microseconds. Overall, we demonstrated significant methodological advances in\n                    <jats:sup>1<\/jats:sup>\n                    H\u2010detected ssNMR spectroscopy, achieving unprecedented\n                    <jats:sup>1<\/jats:sup>\n                    H resolution of rigid glycans in intact fungal cell walls. These developments could be applicable for ssNMR detailed studies of intact cell walls in other human pathogens.\n                  <\/jats:p>","DOI":"10.1002\/cbic.70574","type":"journal-article","created":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T07:06:37Z","timestamp":1792739197000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ultrafast MAS and Deuteration for High\u2010Resolution Proton Detected Solid\u2010State NMR of Intact Fungal Cell Walls"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-8372-3069","authenticated-orcid":false,"given":"Alvis","family":"Zvirgzdins","sequence":"first","affiliation":[{"name":"Latvian Institute of Organic Synthesis  Riga Latvia"},{"name":"Faculty of Medicine and Life Sciences University of Latvia  Riga 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