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The photoactivity of carbons is caused by the combination of high porosity and the presence of photoreactive sites that favor the splitting of the exciton inside the pores, which boosts its efficient use in chemical reactions. The incorporation of O\u2010containing groups in the carbon matrix decreased the photoconversion inside the pores, although values were higher than those attained in solution. This is attributed to the lower stabilization of the exciton through the delocalization within the conjugated sp<jats:sup>2<\/jats:sup> network of the basal planes because of the electron\u2010withdrawing effect of the O\u2010containing groups. The photochemical conversion of light inside the pores is very sensitive to the acidic\/basic nature of the O\u2010containing groups of the carbon matrix, and can be enhanced by balancing the surface composition, porosity, and electronic mobility.<\/jats:p>","DOI":"10.1002\/cctc.201500355","type":"journal-article","created":{"date-parts":[[2015,8,24]],"date-time":"2015-08-24T02:03:10Z","timestamp":1440381790000},"page":"3012-3019","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Tuning the Surface Chemistry of Nanoporous Carbons for Enhanced Nanoconfined Photochemical Activity"],"prefix":"10.1002","volume":"7","author":[{"given":"Leticia F.","family":"Velasco","sequence":"first","affiliation":[]},{"given":"Alicia","family":"Gomis\u2010Berenguer","sequence":"additional","affiliation":[]},{"given":"Joao C.","family":"Lima","sequence":"additional","affiliation":[]},{"given":"Conchi O.","family":"Ania","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2015,8,21]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1098\/rspa.1960.0058"},{"key":"e_1_2_6_3_2","unstructured":"F. 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