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Samples were characterized by BET, XRD, EDX, ICP, TEM, STEM\u2010HAADF, CO<jats:sub>2<\/jats:sub>\u2010TPD, H2\u2010TPR and XPS methods. The order of catalytic activity depended on the support nature for all treated samples, as follows: Au\/La<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/TiO<jats:sub>2<\/jats:sub>&gt;Au\/CeO<jats:sub>2<\/jats:sub>\/TiO<jats:sub>2<\/jats:sub>&gt;Au\/TiO<jats:sub>2<\/jats:sub>. The catalytic activity enhanced with the increase of gold loading in the samples with hydrogen pretreatment, while after the oxidative pretreatment of the catalysts the opposite dependence of the activity with the gold content was found. This catalytic behavior was explained by a change in the surface concentration of monovalent gold ions, which seemed to be the active sites. The most active catalyst, 0.5\u2009% Au\/La<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/TiO<jats:sub>2<\/jats:sub>, pretreated in oxidative atmosphere, had the highest surface concentration of monovalent gold ions.<\/jats:p>","DOI":"10.1002\/cctc.201801566","type":"journal-article","created":{"date-parts":[[2019,1,15]],"date-time":"2019-01-15T22:18:53Z","timestamp":1547590733000},"page":"1615-1624","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Green Oxidation of <i>n<\/i>\u2010Octanol on Supported Nanogold Catalysts: Formation of Gold Active Sites under Combined Effect of Gold Content, Additive Nature and Redox Pretreatment"],"prefix":"10.1002","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2842-2542","authenticated-orcid":false,"given":"E.","family":"Pakrieva","sequence":"first","affiliation":[{"name":"Research School of Chemistry &amp; Applied Biomedical Sciences Tomsk Polytechnic University  Lenin Avenue 30 634050 Tomsk Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5150-6787","authenticated-orcid":false,"given":"E.","family":"Kolobova","sequence":"additional","affiliation":[{"name":"Research School of Chemistry &amp; Applied Biomedical Sciences Tomsk Polytechnic University  Lenin Avenue 30 634050 Tomsk Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7007-8389","authenticated-orcid":false,"given":"G.","family":"Mamontov","sequence":"additional","affiliation":[{"name":"Tomsk State University  Lenin Avenue 36 634050 Tomsk Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0929-3535","authenticated-orcid":false,"given":"N.","family":"Bogdanchikova","sequence":"additional","affiliation":[{"name":"Centro de Nanociencias y Nanotecnolog\u00eda UNAM Post box 14  22860 Ensenada M\u00e9xico"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6726-3804","authenticated-orcid":false,"given":"M. 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