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For well\u2010balanced catalysts, the deposition of Pt in the alumina resulted in lower isomerization selectivity as compared to when platinum was located in the zeolite. In the latter case, the maximal distance between Pt and acid sites was found to be in the nanometric scale (high intimacy) whereas in the former it was in the micrometric scale (low intimacy), particularly due to the presence of large clusters of HUSY zeolite. Nevertheless, whenever proper balance between functions was not ensured in high\u2010intimacy catalysts, the low\u2010intimacy and well\u2010balanced catalysts were shown to perform better. The requirement for nanometric metal\u2010acid sites intimacy must be hence combined with an adequate metal\u2010acid balance to achieve optimal catalytic performance.<\/jats:p>","DOI":"10.1002\/cctc.202000624","type":"journal-article","created":{"date-parts":[[2020,6,5]],"date-time":"2020-06-05T14:35:03Z","timestamp":1591367703000},"page":"4582-4592","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Bifunctional Intimacy and its Interplay with Metal\u2010Acid Balance in Shaped Hydroisomerization Catalysts"],"prefix":"10.1002","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2768-353X","authenticated-orcid":false,"given":"Pedro S. F.","family":"Mendes","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural and Departamento de Engenharia Qu\u00edmica Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. 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