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However, they were previously unused in gas\u2010phase hydrogenation reactions. In this work, we have expanded the applicability of commercially available advanced Ni\/C, NiMo\/C and NiRe\/C materials from electrocatalysis to heterogeneous catalysis of CO<jats:sub>2<\/jats:sub> methanation. Our catalytic testing efforts indicate that the monometallic Ni\/C material demonstrates the best CO<jats:sub>2<\/jats:sub> methanation properties, achieving an excellent CO<jats:sub>2<\/jats:sub> conversion of 83\u2009% at 400\u2009\u00b0C with nearly complete selectivity to CH<jats:sub>4<\/jats:sub> of 99.7\u2009%, plus exhibiting intact performance during 90\u2005h of time\u2010on\u2010stream testing. Such catalytic properties are among the highest reported to date among carbon\u2010supported Ni\u2010based methanation catalysts. 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