{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,12]],"date-time":"2026-02-12T10:26:46Z","timestamp":1770892006968,"version":"3.50.1"},"reference-count":22,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2013,6,11]],"date-time":"2013-06-11T00:00:00Z","timestamp":1370908800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chem Eng &amp;amp; Technol"],"published-print":{"date-parts":[[2013,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Equilibrium data for carbon dioxide and methane adsorption on nanoporous metal organic framework Cu\u2010BTC powder and tablets were measured in a magnetic suspension balance in the temperature range of 308\u2013373\u2009K and a pressure range of 0\u20137\u2009bar and fitted with Langmuir model. The tablets adsorption loading is 0.63\u2009mol\u2009kg<jats:sup>\u20131<\/jats:sup> for methane and 3.1\u2009mol\u2009kg<jats:sup>\u20131<\/jats:sup> for carbon dioxide at 1\u2009bar and 308\u2009K, while these values are 0.77 and 3.9\u2009mol\u2009kg<jats:sup>\u20131<\/jats:sup> for powder in the same conditions. Isosteric heats of adsorption were 22.8 and 15.0\u2009kJ\u2009mol<jats:sup>\u20131<\/jats:sup> for carbon dioxide and methane, respectively, on both adsorbents, which indicates a strong adsorption of carbon dioxide. Also, single and binary breakthrough curves were measured in the same temperature range and atmospheric pressure by using Cu\u2010BTC tablets as adsorbent. A complete model was used in the simulation of breakthrough curves and good agreement was observed with experimental data.<\/jats:p>","DOI":"10.1002\/ceat.201300046","type":"journal-article","created":{"date-parts":[[2013,6,11]],"date-time":"2013-06-11T07:33:34Z","timestamp":1370936014000},"page":"1231-1239","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":43,"title":["CO<sub>2<\/sub>\/CH<sub>4<\/sub> Separation by Adsorption using Nanoporous Metal organic Framework Copper\u2010Benzene\u20101,3,5\u2010tricarboxylate Tablet"],"prefix":"10.1002","volume":"36","author":[{"given":"T.","family":"Asadi","sequence":"first","affiliation":[]},{"given":"M. R.","family":"Ehsani","sequence":"additional","affiliation":[]},{"given":"A. M.","family":"Ribeiro","sequence":"additional","affiliation":[]},{"given":"J. M.","family":"Loureiro","sequence":"additional","affiliation":[]},{"given":"A. 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