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Maximum conversion was achieved by the catalyst with the highest Si\/Al ratio due to faster diffusion of the isomer inside the zeolite channels because of the lower acidity of the solid even with larger crystal size. A kinetic study was then carried out over this catalyst between 473 and 513\u2009K in a batch reactor in the liquid phase. The activation energies obtained do not indicate the presence of diffusional constraints towards any isomer. Finally, the kinetic model obtained was simulated in a fixed\u2010bed reactor and compared to ZSM\u20105 in the temperature range from 493 to 533\u2009K. An increment in <jats:italic>p<\/jats:italic>\u2010xylene production of 20\u2009% on average was obtained.<\/jats:p>","DOI":"10.1002\/ceat.201500219","type":"journal-article","created":{"date-parts":[[2015,10,19]],"date-time":"2015-10-19T13:57:01Z","timestamp":1445263021000},"page":"225-232","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Xylene Isomerization in the Liquid Phase Using Large\u2010Pore Zeolites"],"prefix":"10.1002","volume":"39","author":[{"given":"Jonathan C.","family":"Gon\u00e7alves","sequence":"first","affiliation":[]},{"given":"Al\u00edrio E.","family":"Rodrigues","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2015,12,11]]},"reference":[{"key":"e_1_2_7_1_2","volume-title":"Advances in Nanoporous Materials","author":"Perego C.","year":"2009"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2014.07.006"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/i260074a011"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2010.03.077"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1080\/01614940.2013.822266"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.3923\/jas.2005.236.248"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2012.04.100"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201300824"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2010.12.031"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/0166\u20109834(82)80132\u20102"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie100527x"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/crat.200800149"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2013.02.040"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527610044.hetcat0057"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/i360057a007"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/0021\u20109517(82)90271\u20108"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjce.5450610104"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie00058a006"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.3303\/CET0917015"},{"key":"e_1_2_7_20_2","doi-asserted-by":"crossref","unstructured":"J. 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