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Herein, we report an inverted F\u2010type heterojunction composed of ZnWO\n                    <jats:sub>4<\/jats:sub>\n                    \/In\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    (ZWO\/IS) that delivers exceptional photocatalytic performance while preserving strong oxidation potentials. By using work function engineering, we establish a built\u2010in electric field that facilitates asymmetric charge separation, with photogenerated electrons from directed ZWO to IS and holes retained in ZWO to drive oxidative reactions. This unique charge transfer mechanism is directly captured via in situ X\u2010ray photoelectron spectroscopy (XPS), Kelvin probe force microscopy (KPFM), revealing a marked reduction in carrier recombination lifetime compared to pristine IS. The ZWO\/IS heterojunction achieves outstanding degradation efficiency for tetracycline hydrochloride (TCH), with three distinct detoxification pathways elucidated through high\u2010performance liquid chromatography\u2010mass spectrometry (HPLC\u2010MS) and density functional theory (DFT) calculations. Comprehensive toxicity assessments, including microbial viability tests, phytotoxicity assays, and mammalian cell studies, confirm complete detoxification, with degradation by\u2010products exhibiting negligible developmental toxicity and mutagenicity. This work positions inverted F\u2010type heterojunctions as transformative platforms for photocatalytic water treatment, effectively integrating interfacial band engineering, scalable reactor design, and process optimization to bridge the gap between mechanistic insight and real\u2010world applications.\n                  <\/jats:p>","DOI":"10.1002\/cey2.70179","type":"journal-article","created":{"date-parts":[[2026,2,9]],"date-time":"2026-02-09T11:12:16Z","timestamp":1770635536000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Rational Design of Inverted F\u2010Type Heterojunctions for Photocatalytic Emerging Contaminant Degradation"],"prefix":"10.1002","author":[{"given":"Yanxian","family":"Jin","sequence":"first","affiliation":[{"name":"Zhejiang Key Laboratory of New Drug Development for Central Nervous System Diseases Taizhou University Taizhou Zhejiang 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