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In contrast, related oxides of molybdenum (MoO<jats:sub>3<\/jats:sub>) and vanadium (V<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>) do not activate H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> under comparable conditions. The active rhenium peroxo complex was isolated from the system Re<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>\/H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>: the crystalline red\u2010orange, <jats:italic>explosive<\/jats:italic> compound of formula H<jats:sub>4<\/jats:sub>Re<jats:sub>2<\/jats:sub>O<jats:sub>13<\/jats:sub> is the most oxygen rich rhenium compound isolated to date. Its structure resembles a \u201cperoxo perrhenic acid\u201d. The binuclear compound could be isolated in the form of a diglyme adduct, structurally defined as two corner\u2010sharing pentagonal bipyramids with apical oxo and aquo ligands; the equatorial positions are occupied by the bridging oxygen and by <jats:italic>n<\/jats:italic><jats:sup>2<\/jats:sup>\u2010peroxo groups (two [O<jats:sub>2<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> ligands per rhenium). In contrast to the known complex [CH<jats:sub>3<\/jats:sub>ReO(O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>].H<jats:sub>2<\/jats:sub>O, the new peroxo species [O{ReO(O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>.H<jats:sub>2<\/jats:sub>O}<jats:sub>2<\/jats:sub>] decomposes hydrolytically during the catalytic cycle and can thus not compete in terms of catalytic activity in oxidation reactions involving H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>. Hydrolysis yields \u201cperrhenic acid\u201d Re<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>.2H<jats:sub>2<\/jats:sub>O, the diglyme adduct of which compound was also characterized by means of an X\u2010ray diffraction analysis.<\/jats:p>","DOI":"10.1002\/chem.19960020208","type":"journal-article","created":{"date-parts":[[2007,7,20]],"date-time":"2007-07-20T19:02:49Z","timestamp":1184958169000},"page":"168-173","source":"Crossref","is-referenced-by-count":68,"title":["The \u201cPeroxo Perrhenic Acid\u201d H<sub>4<\/sub>Re<sub>2<\/sub>O<sub>13<\/sub>: An Oxygen\u2010Rich Metal Peroxide and Oxidation Catalyst"],"prefix":"10.1002","volume":"2","author":[{"given":"Wolfgang A.","family":"Herrmann","sequence":"first","affiliation":[]},{"given":"Jo\u00e3o D. G.","family":"Correia","sequence":"additional","affiliation":[]},{"given":"Fritz E.","family":"K\u00fchn","sequence":"additional","affiliation":[]},{"given":"Georg R. 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